Insitu microparticle diagnostics by stimulated Raman scattering
文献信息
A novel technique for the identification of the chemical composition of microdroplets has been developed. External seeding of stimulated Stokes Raman scattering (SSRS) has been applied to reduce the minimum detectable concentration of the minority species in multicomponent microdroplets. To avoid complications with polarizer and analyzer in remote sensing applications, we utilize the fact that the probed (seeded) SSRS band of the minority species (at νmin) can efficiently pump SSRS of the majority species (at νmaj). The Raman signal of the minority species appears at a shift of νmin+maj, which can easily be distinguished from the elastically scattered light of the seed laser at the shift of νmin. Furthermore, we investigated fluorescing microdroplets with stimulated anti-stokes Raman scattering (SARS).
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














