Dynamics and dissipation in an externally forced system

文献信息

发布日期 2000-08-11
DOI 10.1039/B004443L
影响因子 3.676
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摘要

We study numerically the influence of periodic and random external perturbations on the oscillating Selkov model by varying one dimensionless parameter, κ, of the model. When the variations of κ are periodic in time, the system responds with bursting oscillations in the case where the forcing frequency is different from the frequency of the oscillations without any perturbations. When the frequencies are almost equal, the system responds to the forcing by oscillating with almost the same frequency as the forcing, but with a higher amplitude linearly proportional to the amplitude of the perturbation. In the second case, κ varies randomly with time. The dynamics are described by stochastic differential equations. The computed ensemble averages of concentrations exhibit a decay or localization of the limit cycle for small amplitudes of the noise. This decay is faster when the amplitude of the noise is higher. As the noise amplitude increases, chaotic behavior begins to appear. For noise amplitudes high enough to push the system away from the oscillatory region, the system exhibits high-amplitude intermittent bursts in the concentrations for different realizations of the noise. We also computed the chemical entropy production for all the cited cases. When κ varies periodically with the same frequency, the entropy production increases nonlinearly with the amplitude of the forcing; the amplitude of the oscillations increases only linearly with the amplitude of the forcing. In general, when the system is periodically forced, strips of high dissipation and valleys of low dissipation exist in the space formed by the amplitude of the perturbation and winding number. In the second case, where κ is random the overall average entropy production is insensitive to the amplitude of the noise as long as κ does not leave the oscillatory region. When κ begins to cross into other regions, the overall average entropy production increases almost linearly with the amplitude of the noise.

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来源期刊

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
自引率: 10.3%
年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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