Dynamics and dissipation in an externally forced system
文献信息
We study numerically the influence of periodic and random external perturbations on the oscillating Selkov model by varying one dimensionless parameter, κ, of the model. When the variations of κ are periodic in time, the system responds with bursting oscillations in the case where the forcing frequency is different from the frequency of the oscillations without any perturbations. When the frequencies are almost equal, the system responds to the forcing by oscillating with almost the same frequency as the forcing, but with a higher amplitude linearly proportional to the amplitude of the perturbation. In the second case, κ varies randomly with time. The dynamics are described by stochastic differential equations. The computed ensemble averages of concentrations exhibit a decay or localization of the limit cycle for small amplitudes of the noise. This decay is faster when the amplitude of the noise is higher. As the noise amplitude increases, chaotic behavior begins to appear. For noise amplitudes high enough to push the system away from the oscillatory region, the system exhibits high-amplitude intermittent bursts in the concentrations for different realizations of the noise. We also computed the chemical entropy production for all the cited cases. When κ varies periodically with the same frequency, the entropy production increases nonlinearly with the amplitude of the forcing; the amplitude of the oscillations increases only linearly with the amplitude of the forcing. In general, when the system is periodically forced, strips of high dissipation and valleys of low dissipation exist in the space formed by the amplitude of the perturbation and winding number. In the second case, where κ is random the overall average entropy production is insensitive to the amplitude of the noise as long as κ does not leave the oscillatory region. When κ begins to cross into other regions, the overall average entropy production increases almost linearly with the amplitude of the noise.
相关文献
Intermolecular network analysis of the liquid and vapor interfaces of pentane and water: microsolvation does not trend with interfacial properties
Yasaman Ghadar, Aurora E. Clark
DOI: 10.1039/C4CP00602J
Carbon dioxide reduction via light activation of a ruthenium–Ni(cyclam) complex
Christian Herrero, Annamaria Quaranta, Sanae El Ghachtouli, Winfried Leibl
DOI: 10.1039/C3CP54946A
Thermoresponsive fluorescence of a graphene–polymer composite based on a local surface plasmon resonance effect
Yunyun Huang, Wensheng Lin, Kan Chen, Wenkai Zhang, Xudong Chen, Ming Qiu Zhang
DOI: 10.1039/C4CP00773E
Self-healing mechanism of metallopolymers investigated by QM/MM simulations and Raman spectroscopy
Julien Guthmuller
DOI: 10.1039/C4CP00562G
Development of high power and energy density microsphere silicon carbide–MnO2 nanoneedles and thermally oxidized activated carbon asymmetric electrochemical supercapacitors
Myeongjin Kim, Jooheon Kim
DOI: 10.1039/C4CP01141D
Photophysical properties of open-framework germanates templated by nickel complexes
M. V. Peskov, U. Schwingenschlögl
DOI: 10.1039/C4CP00836G
Interplay between the ionic and electronic transport and its effects on the reaction pattern during the electrochemical conversion in an FeF2 nanoparticle
Ying Ma, Stephen H. Garofalini
DOI: 10.1039/C4CP00481G
Effect of post-treatments on the photocatalytic activity of Sm2Ti2S2O5 for the hydrogen evolution reaction
Wen Zhao, Fuxiang Zhang, Takashi Hisatomi, Kazunari Domen
DOI: 10.1039/C3CP54668C
Clusters in the adsorbates of vapours and gases: Zeta isotherm approach
Seyed Hadi Zandavi, Charles A. Ward
DOI: 10.1039/C4CP00843J
Flow dependent performance of microfluidic microbial fuel cells
Daniele Vigolo, Talal T. Al-Housseiny, Yi Shen, Fiyinfoluwa O. Akinlawon, Saif T. Al-Housseiny, Ronald K. Hobson, Amaresh Sahu, Katherine I. Bedkowski, Thomas J. DiChristina, Howard A. Stone
DOI: 10.1039/C4CP01086H
您可能还喜欢
如何储存8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯(CAS号:1072944-81-0)?
8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯应储存在阴凉、干燥的地方,避免光照和高温。建议使用密封容器进行储存,以防止水分和空气的影响。
2,2-二(2-呋喃基)丙烷(CAS号:17920-88-6)的市场或研究趋势如何?
2,2-二(2-呋喃基)丙烷的研究趋势主要集中在新型材料的开发和应用,如高分子材料、有机光电材料等。市场趋势方面,随着环保要求的提高和新材料的应用,该化合物的需...
如何处理含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐(CAS号:475152-31-9)的废料?
对于含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐的废料,应首先进行分类和分离,以减少危险物质的数量。随后,可以考虑通过化学氧化、生物...
Cinnamyl 3-aminobut-2-enoate(CAS号:113898-97-8)安全吗?
Cinnamyl 3-氨基丁-2-烯酸在接触皮肤和眼睛时可能会引起刺激。应避免吸入其粉尘和烟雾。操作时应穿戴适当的个人防护装备,如手套、护目镜和实验室外套。
反式-2-十二碳烯二酸(CAS号:6402-36-4)的市场或研究趋势如何?
反式-2-十二碳烯二酸在医药、材料科学等领域有一定的应用,但其市场相对较小。近年来,由于环保意识的提升,对环境友好型化学品的需求增加,研究倾向于开发更绿色的合成...
什么是(9ci)-1H-苯并咪唑-5-乙酸(CAS号:473895-86-2)?
(9ci)-1H-苯并咪唑-5-乙酸是一种含氮杂环化合物,其化学结构为1H-苯并咪唑-5-乙酸。该化合物具有特定的分子式C8H7NO2,属于有机酸类化合物。
酞菁蓝(CAS号:147-14-8)的主要用途是什么?
酞菁蓝主要用作颜料和染料,广泛应用于塑料、油墨、涂料、纺织品及橡胶工业中。它也用于光敏材料,如太阳能电池和光刻胶。在医疗领域,酞菁蓝因其光敏特性被用于某些光动力...
5-甲基-1,2,3,4-四氢异喹啉(CAS号:123593-99-7)安全吗?
5-甲基-1,2,3,4-四氢异喹啉在使用和储存时需要谨慎处理。它具有一定的毒性,应避免吸入其蒸气或直接接触皮肤和眼睛。操作此化合物时,建议佩戴防护眼镜、实验服...
如何处理含有3',4',5'-三甲氧基苯乙酮(CAS号:1136-86-3)的废料?
含有3',4',5'-三甲氧基苯乙酮的废液应首先确保其是否为危险废物,根据当地法规确定处理方法。通常,这类有机废液可以采用中和反应降低其pH值,然后通过蒸馏或萃...
如何储存KI-7(CAS号:1489263-00-4)?
KI-7应储存在通风良好的干燥环境中,避免光照和高温。建议使用密封容器储存,并保持在阴凉处。储存温度应控制在室温范围内,一般建议不超过25°C。避免与氧化剂接触...
来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure S-[2,3-Bis(palmitoyloxy)propyl]-N-[(9H-fluoren-9-ylmethoxy)(hydroxy)methylene]cysteine structure](https://cnstatic.chemtradehub.com/structs/210/210532-98-2-f6a7.webp)


