Hydrogen evolution reaction on a smooth iron electrode in alkaline solution at different temperatures
文献信息
The hydrogen evolution reaction (HER) has been studied on a rotating polycrystalline smooth iron disc electrode in the temperature range 20⩽T/°C⩽60 in 2 M NaOH. It has been demonstrated that only for ∣η∣0.1 V can the polarisation curve be considered as that corresponding to the HER, due to the corrosion process that takes place at low overpotentials. The experimental results were adequately correlated by the Volmer–Heyrovsky–Tafel mechanism with a Langmuirian adsorption, considering αV≠αH. On this basis, two sets of kinetic parameters were found for each of the three elementary steps and the corresponding apparent activation energies were also evaluated. These results allowed the calculation of the experimental kinetic parameters, Tafel slope and extrapolated exchange current density, for all the temperatures studied.
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来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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