Electrodeposition at polarisable liquid|liquid interfaces: The role of interfacial tension on nucleation kinetics
文献信息
Christoffer Johans, Peter Liljeroth, Kyösti Kontturi
The influence of surfactants on nucleation at liquid|liquid interfaces was studied by cyclic voltammetry and chronoamperometry. The surface activity of a nanoparticle was considered within classical thermodynamics. These considerations indicated that while large particles preferentially reside in the interfacial region, small particles are not surface active. This results in a second critical radius in nucleation experiments. The experiments where the interfacial tension was changed by addition of a surfactant were in line with theoretical predictions.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




