The first structural characterization and determination of the isomerization activation parameters of a chiral phosphatitanocene
文献信息
T. Keith Hollis, Yi Joon Ahn, Fook S. Tham
The activation parameters (ΔG‡298 = 11.5 (±1.0) kcal mol−1, ΔH‡ = 16.3 (±3.0) kcal mol−1, ΔS‡ = 16 (±11) cal mol−1 K−1) have been determined for the rac to meso isomerization of a phosphametallocene, bis(3,4-dimethyl-2-phenylphospholyl)titanium dichloride, 2, which has been structurally characterized.
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