Remarkable axial ligand effect on regioselectivity towards terminal alkenes in epoxidation of dienes by a robust manganese porphyrin

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发布日期 2003-01-28

DOI 10.1039/B210645K

影响因子 6.222

作者

Tat-Shing Lai, Stephen K. S. Lee, Lam-Lung Yeung, Hai-Yang Liu, Ian D. Williams, Chi K. Chang

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摘要

With a highly encumbered manganese porphyrin as catalyst, significant improvements in regioselectivity towards less substituted C–C double bond in diene epoxidation were attained by simply adding organic bases as axial ligand.

期刊推荐

Chemical Society Reviews

Chemistry Letters

Corrosion Reviews

Fire and Materials

Organometallics

Composites Science and Technology

Geotextiles and Geomembranes

Heterocycles

Journal of the Royal Society of New Zealand

Composite Structures

来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Remarkable axial ligand effect on regioselectivity towards terminal alkenes in epoxidation of dienes by a robust manganese porphyrin

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