Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidine
文献信息
Nicholas Dummer, David J. Willock, Stuart H. Taylor, Richard P. K. Wells, Peter B. Wells, Graham J. Hutchings
Pt supported on α-Al2O3, γ-Al2O3 and SiO2 pre-modified with cinchonidine gives over 50% ee in the hydrogenation of methyl pyruvate to methyl lactate using gas phase reactants at 40 °C giving the first clear observation of high enantioselection at the gas/solid interface.
相关文献
Boosting the electrocatalytic hydrogen evolution and sodium-storage properties of Co9S8 nanoparticles via encapsulation with nitrogen-doped few-layer graphene networks
Lizhi Qian, Zhiqiang Wei, Tingli Yu, Bingdong Chang, Hongyu Sun, Wei Huang
DOI: 10.1039/D1SE00829C
Methane pyrolysis in low-cost, alkali-halide molten salts at high temperatures
Clarke Palmer, Maryam Tarazkar, Michael J. Gordon, Horia Metiu, Eric W. McFarland
DOI: 10.1039/D1SE01408K
A graphitic carbon nitride metal-free visible light photocatalyst with controllable carbon self-doping towards efficient hydrogen evolution
Lin Lei, Weijia Wang, Zhengfeng Xie, Xiaobo Wu, Arun Kumar Yadav, Huiqing Fan
DOI: 10.1039/D1SE01244D
Self-shape-transformable 3D tessellated bifacial crystalline Si solar cell module enabling extra energy gain through intervals and an integrated actuator
Min Ju Yun, Dong Yoon Lee
DOI: 10.1039/D1SE01205C
Highly ionic conductive and mechanically strong MXene/CNF membranes for osmotic energy conversion
Zhe Sun, Zongxia Gao, Zhu Shan, Liangmao Xu
DOI: 10.1039/D1SE01729B
Rich-phosphorus/nitrogen co-doped carbon for boosting the kinetics of potassium-ion hybrid capacitors
Zhenyu Xie, Daping Qiu, Min Li
DOI: 10.1039/D1SE01627J
Bifunctional manganese oxide–silver nanocomposites anchored on graphitic mesoporous carbon to promote oxygen reduction and inhibit cathodic biofilm growth for long-term operation of microbial fuel cells fed with sewage
Dena Z. Khater, R. S. Amin, Amani E. Fetohi, K. M. El-Khatib, Mohamed Mahmoud
DOI: 10.1039/D1SE01479J
Carbazole-based D–A type hole transport materials to enhance the performance of perovskite solar cells
Bizu He, Huiqiang Lu, Rong Tang, Fei Wu, Cheng Zhong, Shufang Li, Jinliang Wang, Linna Zhu
DOI: 10.1039/D1SE01251G
A three-dimensional coral-like Zn,O-codoped Ni3S2 electrocatalyst for efficient overall water splitting at a large current density
Liyun Cao, Yifei Zhang, Liangliang Feng, Danyang He, Qianqian Liu, Yingbo Gong, Guodong Li, Jianfeng Huang
DOI: 10.1039/D1SE01708J
您可能还喜欢
甲基双烯双酮(CAS号:5173-46-6)通常如何合成?
甲基双烯双酮可以通过多种途径合成。一种常见的合成方法是通过甲基化和环化反应,先由4-甲基-9-烯-1,3-二酮合成,然后进行环化反应得到目标产物。具体的合成路线...
如何处理含有tert-butyl 3,5-difluorobenzoate(CAS号:467442-11-1)的废料?
处理含有tert-butyl 3,5-difluorobenzoate(CAS号:467442-11-1)的废液时,应首先收集并密封,避免泄漏。随后,建议通过焚...
4-二甲氧基甲基-2-(三氟甲基)嘧啶(CAS号:878760-47-5)通常如何合成?
4-二甲氧基甲基-2-(三氟甲基)嘧啶通常通过三氟甲基化反应合成。首先,将2-氯嘧啶与三氟甲基锂在惰性溶剂中反应,然后将得到的三氟甲基化中间体与二甲氧基甲基化试...
WRW4(CAS号:878557-55-2)的主要用途是什么?
WRW4主要应用于科学研究领域,尤其是在合成化学和有机合成方面。由于其特殊的化学性质,它可能被用于特定的化学反应或合成过程。
什么是6-O-(三异丙基硅基)-D-葡萄烯糖(CAS号:137915-37-8)?
6-O-(三异丙基硅基)-D-葡萄烯糖是一种有机化合物,化学名为1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-ar...
N-Benzyl-N,N-dimethyl-2-phenoxyethanaminium(CAS号:7181-73-9)的主要用途是什么?
N-Benzyl-N,N-dimethyl-2-phenoxyethanaminium在有机合成中被用作保护基团,可以用于保护氨基,提高反应的选择性和产率。此外...
什么是3-(Cyclohex-1-en-1-yl)acrylic acid(CAS号:56453-88-4)?
3-(Cyclohex-1-en-1-yl)acrylic acid,简称3-环己烯-1-烯丙酸,是一种含有环己烯基团的丙烯酸衍生物,用于合成其他化合物或作为有...
如何储存(1R)-7-fluoro-1,2,3,4-tetrahydronaphthalen-1-amine(CAS号:1055949-62-6)?
应将(1R)-7-氟-1,2,3,4-四氢萘胺储存于阴凉、干燥、通风良好的地方,远离火源和热源。避免与氧化剂、酸类接触。使用合适的容器,密封保存。
3-甲基苯并呋喃-2-羧酸(CAS号:24673-56-1)的主要用途是什么?
3-甲基苯并呋喃-2-羧酸主要用作合成其他化合物的中间体,如药物合成、有机合成等领域。此外,该化合物在某些领域作为化学试剂或分析试剂使用。
孕烷醇酮(CAS号:128-20-1)适用哪些法规指南?
孕烷醇酮(CAS号:128-20-1)需遵守GHS(全球化学品统一分类和标签制度)的相关分类和标签要求,主要涉及健康危害、环境危害和物理化学危害。此外,还需要遵...
来源期刊
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure 3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure](https://cnstatic.chemtradehub.com/structs/861/861249-77-6-025b.webp)


