Exo-metal coordination by a tricyclic [{P(µ-N-2-NC5H4)}2(µ-O)]2 dimer in [{P(µ-N-2-NC5H4)}2(µ-O)]2{CuCl·(C5H5N)2}4 {2-NC5H4 = 2-pyridyl, C5H5N = pyridine)

文献信息

发布日期 2003-11-03
DOI 10.1039/B309842G
影响因子 6.222
作者

Andrew D. Bond, Emma L. Doyle, Felipe García, Richard A. Kowenicki, Mary McPartlin, Lucía Riera, Dominic S. Wright


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摘要

The in situ reaction of the phosphazane dimer [ClP(µ-N-2-NC5H4)]2 (2) with CuCl in the presence of C5H5N/H2O gives the title complex [{P(µ-N-2-NC5H4)}2(µ-O)]2{CuCl·(C5H5N)2}4 (1), containing a tricyclic [{P(µ-N-2-NC5H4)}2(µ-O)]2 ligand which is isoelectronic with species of the type [{P(µ-NR)}2NR]2.

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Chemical Communications

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