Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

文献信息

发布日期 2008-01-24

DOI 10.1039/B715502F

影响因子 6.222

作者

Anna Proust, René Thouvenot, Pierre Gouzerh

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摘要

Functionalization via covalent grafting of organic functions allows to tune the redox and acid–base properties, and the solubility of polyoxometalates, to enhance their stability and biological activity and to reduce their toxicity, to facilitate their implementation in extended structures and functional devices. We discuss herein the electronic and binding connections, and the various synthesis methodologies. We emphasize on organonitrogen, organosilyl and organophosphonyl derivatives with special attention to synthesis, characterization and potential applications in catalysis and materials science. We also consider the giant molybdenum oxide-based clusters especially the porous capsule-type clusters (Keplerates) which have high relevance to this context.

期刊推荐

Chemical & Pharmaceutical Bulletin

Chemistry of Natural Compounds

Advances in Colloid and Interface Science

Journal of the American Chemical Society

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Australian Journal of Chemistry

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Accounts of Chemical Research

Carbon

来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

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来源期刊

Chemical Communications

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