![2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure](https://cnstatic.chemtradehub.com/structs/567/56718-70-8-f037.webp "2-{[4-(2-Methoxyethyl)phenoxy]methyl}oxirane structure")
Preparation and structure of the unique silicon(iv) cation [SiF3(Me3tacn)]+
文献信息
发布日期
2009-02-10
DOI
10.1039/B822236C
影响因子
6.222
作者
Fei Cheng, Andrew L. Hector, William Levason, Gillian Reid, Michael Webster, Wenjian Zhang
查看原文
摘要
The trifluorosilicon(IV) cation [SiF3(Me3tacn)]+, isolated as salts with [SiF5]−, [B{3,5-(CF3)2C6H3}4]− or Cl−, is obtained by reaction of SiF4 with Me3tacn under anhydrous conditions, and compared with the tetrafluoro complexes [SiF4(tmeda)] and [SiF4{κ2-Me2N(CH2)2NMe(CH2)2NMe2(CH2Cl)}][SiF5] obtained with the acyclic di- and tri-amines.
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来源期刊
Chemical Communications
CiteScore:
8.6
自引率:
4.7%
年发文量:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
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