Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile

文献信息

发布日期 2009-04-06
DOI 10.1039/B902162K
影响因子 6.222
作者

Li-Rong Guo, Song-Song Bao, Yi-Zhi Li, Li-Min Zheng


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摘要

A general approach to obtain pyrophosphonates is achieved by reacting arylphosphonic acids with AgNO3 in CH3CN under solvothermal conditions; the process is coupled with the C–C bond cleavage of acetonitrile and the formation of novel complexes [Agn(RPO2(O)O2PR)m](CN); the mechanism of the process is proposed.

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来源期刊

Chemical Communications

Chemical Communications
CiteScore: 8.6
自引率: 4.7%
年发文量: 2458

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