Ag(i)-mediated formation of pyrophosphonate coupled with C–C bond cleavage of acetonitrile
文献信息
Li-Rong Guo, Song-Song Bao, Yi-Zhi Li, Li-Min Zheng
A general approach to obtain pyrophosphonates is achieved by reacting arylphosphonic acids with AgNO3 in CH3CN under solvothermal conditions; the process is coupled with the C–C bond cleavage of acetonitrile and the formation of novel complexes [Agn(RPO2(O)O2PR)m](CN); the mechanism of the process is proposed.
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Chemical Communications

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