Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals

文献信息

发布日期 2010-09-06

DOI 10.1039/C0PY00245C

影响因子 5.582

作者

Elena Chernikova, Vladimir Golubev, Anatoly Filippov, Ching Yeh Lin, Michelle L. Coote

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摘要

Spin traps have been used to obtain the first direct experimental determination of the addition (5 × 106 L mol−1 s−1), fragmentation (8 × 10−3 s−1) and self-termination (6.5 × 102 L mol−1 s−1) rate coefficients in RAFT polymerization using the interaction of a tert-butyl radical with tert-butyl dithiobenzoate at ambient temperature as a model reaction.

期刊推荐

Journal of Dispersion Science and Technology

Annual Review of Public Health

Crystal Research and Technology

Dyes and Pigments

Pharmacology & Therapeutics

European Journal of Medicinal Chemistry

Tetrahedron Letters

Studies in Conservation

Applied Clay Science

Progress in Materials Science

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals

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