Weak Ag⋯Ag and Ag⋯π interactions in templating regioselective single and double [2+2] reactions of N,N′-bis(3-(4-pyridyl)acryloyl)–hydrazine: synthesis of an unprecedented tricyclohexadecane ring system

文献信息

发布日期 2011-08-22
DOI 10.1039/C1CC13994K
影响因子 6.222
作者

Ramkinkar Santra, Kaustuv Banerjee, Kumar Biradha


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摘要

Synthesis of a stereospecific four–twelve–four fused tricyclic compound containing a tetraamide macrocycle has been achieved by the solid state [2+2] reaction through utilization of Ag⋯Ag interaction. The influence of anions on crystal packing has been utilized for the synthesis of a regioselective mono cyclobutane compound via the Ag⋯π interactions.

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来源期刊

Chemical Communications

Chemical Communications
CiteScore: 8.6
自引率: 4.7%
年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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