Catalytic chain transfer and its derived macromonomers

文献信息

发布日期 2011-07-26

DOI 10.1039/C1PY00224D

影响因子 5.582

作者

Johan P. A. Heuts, Niels M. B. Smeets

查看原文

摘要

An overview is given of cobalt-catalyzed chain transfer in free-radical polymerization and the chemistry and applications of its derived macromonomers. Catalytic chain transfer polymerization is a very efficient and versatile technique for the synthesis of functional macromonomers. Firstly the mechanism and kinetic aspects of the process are briefly discussed in solution/bulk and in emulsion polymerization, followed by a description of its application to produce functional macromonomers. The second part of this review briefly describes the behavior of the macromonomers as chain transfer agents and/or comonomers in second-stage radical polymerizations yielding polymers of more complex architectures. The review ends with a brief overview of post-polymerization modifications of the vinyl endfunctionality of the macromonomers yielding functional polymers with applications ranging from initiators in anionic polymerization to end-functional lectin-binding glycopolymers.

期刊推荐

Advanced Engineering Materials

Contact Lens & Anterior Eye

Journal of Enzyme inhibition and Medicinal Chemistry

Angewandte Chemie International Edition

Mini-Reviews in Medicinal Chemistry

Faraday Discussions

Lab on a Chip

European Journal of Organic Chemistry

Nature Reviews Drug Discovery

Photochemical & Photobiological Sciences

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Catalytic chain transfer and its derived macromonomers

文献信息

期刊推荐

相关文献

Understanding charge storage in Nb2CTx MXene as an anode material for lithium ion batteries

Core-softened water–alcohol mixtures: the solute-size effects

Attosecond charge migration following oxygen K-shell ionization in DNA bases and base pairs

Generation, contraction, and polarisation of Gaussian basis sets for atomic and molecular calculations using the generator coordinate method with polynomial discretisation: atoms from Na through Cl

New complexes of liquid crystal discotic triphenylenes: induction of the double gyroid phase

A graphene–Mo2C heterostructure for a highly responsive broadband photodetector

B-Doped 2D-InSe as a bifunctional catalyst for CO2/CH4 separation under the regulation of an external electric field

Active Brownian particle in homogeneous media of different viscosities: numerical simulations

Theoretical study of spodium bonding in the active site of three Zn-proteins and several model systems

Scouting for strong light–matter coupling signatures in Raman spectra

您可能还喜欢

2-(甲基磺酰基)嘧啶-5-胺(CAS号：56621-92-2)适用哪些法规指南？

在合成中是否有4-(4-氯苯基)-1H-咪唑(CAS号：35512-29-9)的替代品？

什么是N~2~-甲基丙氨酸酰胺(CAS号：32012-16-1)？

如何处理含有N-苄基-3-氨基氧杂环丁烷草酸盐(CAS号：1956341-96-0)的废料？

4-bromo-2-chloro-6-methylbenzoic acid(CAS号：877149-07-0)的物理化学性质是什么？

2-[(2,5-二氯-4-嘧啶)氨基]-N-甲基苯甲酰胺(CAS号：761440-08-8)通常如何合成？

1,4-二氯肽嗪(CAS号：4752-10-7)安全吗？

在合成中是否有3,5-二溴-4-甲基苯胺(CAS号：13194-73-5)的替代品？

2-氯喹啉-4-羧酸甲酯(CAS号：62482-26-2)的主要用途是什么？

i>]吡啶(CAS号：474708-88-8)安全吗？

来源期刊

Polymer Chemistry

推荐化合物

2-Ethoxy-3,4-dihydro-2H-pyran

1-Bromo-2-chloro-4-methoxybenzene

2-Cyano-N-ethylacetamide

Allyl diethyl phosphate

5-Methoxy-1H-pyrrolo[3,2-b]pyridine

推荐供应商