Tribenzotriquinacene-based polymers of intrinsic microporosity

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发布日期 2011-08-11

DOI 10.1039/C1PY00294E

影响因子 5.582

作者

James Vile, Mariolino Carta, C. Grazia Bezzu, Neil B. McKeown

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摘要

Bowl-shaped tribenzotriquinacene (TBTQ) derivatives containing hydroxyl groups at their peripheral sites are successful monomers for the synthesis of polymers of intrinsic microporosity (PIMs) with examples of both network and non-network PIMs demonstrated. Nitrogen adsorption measurements reveal apparent surface areas in the range of 560–670 m2 g−1 for the TBTQ-PIMs. A network structure and i-propyl, rather than methyl substitution at the apical site of the TBTQ unit, appear to favour porosity.

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来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Tribenzotriquinacene-based polymers of intrinsic microporosity

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来源期刊

Polymer Chemistry

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