Is ballistic transportation or quantum confinement responsible for changes in the electrical properties of thin polymer films?
文献信息
Jean-Pierre Veder, Kunal Patel, Junqiao Lee, Muhammad Tanzirul Alam, Andrew Nelson, Roland De Marco
Resistivities of thin polymer films increase abruptly with decreasing thickness, although the corresponding decline in resistance plateaus below a certain thickness. One can jump to the incorrect conclusion that quantum confinement and surface scattering are responsible for this behaviour, and we highlight the pitfalls of committing such an error.
相关文献
A novel cyclodextrin-containing pH-responsive star polymer for nanostructure fabrication and drug delivery
Mingming Zhang, Qingqing Xiong, Jinqian Chen, Yinsong Wang
DOI: 10.1039/C3PY00656E
Photo-responsive linear and cross-linked supramolecular polymers based on host–guest interactions
Shengyi Dong, Lingyan Gao, Jinying Li, Donghua Xu, Qizhong Zhou
DOI: 10.1039/C3PY00494E
A nondestructive, statistical method for determination of initiation efficiency: dipentaerythritol-aided synthesis of ternary ABC3 miktoarm stars using a combined “arm-first” and “core-first” approach
Alexander A. Steinschulte, Bjoern Schulte, Natascha Drude, Michael Erberich, Christian Herbert, Jun Okuda, Martin Möller, Felix A. Plamper
DOI: 10.1039/C3PY00444A
Synthesis and gas permeation properties of novel spirobisindane-based polyimides of intrinsic microporosity
Yulia Rogan, Ludmila Starannikova, Victoria Ryzhikh, Yuri Yampolskii, Paola Bernardo, Fabio Bazzarelli, Johannes Carolus Jansen, Neil B. McKeown
DOI: 10.1039/C3PY00451A
A new method to make polymers with flexible main chains and photoelectric pendants for organic semiconductors
Yeli Fan, Baoping Lin, Ying Sun, Xiaohui Gong, Hong Yang, Xueqin Zhang
DOI: 10.1039/C3PY00454F
Highly structured pH-responsive honeycomb films by a combination of a breath figure process and in situthermolysis of a polystyrene-block-poly(ethoxy ethyl acrylate) precursor
Wim Van Camp, Filip Du Prez, Laurent Rubatat, Laurent Billon, Maud Save
DOI: 10.1039/C3PY00643C
RAFT copolymerization of alginate-derived macromonomers – synthesis of a well-defined poly(HEMAm)-graft-(1→4)-α-l-guluronan copolymer capable of ionotropic gelation
Ali Ghadban, Eric Reynaud, Marguerite Rinaudo, Luca Albertin
DOI: 10.1039/C3PY00730H
Solution-processable blue-to-transmissive electrochromic benzotriazole-containing conjugated polymers
Wei Teng Neo, Lee May Loo, Jing Song, Xiaobai Wang, Ching Mui Cho, Hardy Sze On Chan, Yun Zong
DOI: 10.1039/C3PY00677H
One-step facile synthesis of monodisperse raspberry-like P(S–MPS–AA) colloidal particles
Yangyi Sun, Yuyong Yin, Min Chen, Shuxue Zhou, Limin Wu
DOI: 10.1039/C3PY21155J
π-Congested poly(paraphenylene) from 2,2′,6,6′-tetraphenyl-1,1′-biphenyl units: synthesis and structural characterization
Florian Schlütter, Tomohiko Nishiuchi, Volker Enkelmann, Klaus Müllen
DOI: 10.1039/C3PY00166K
您可能还喜欢
(3-氨苯基)环丙基甲酮(CAS号:162174-75-6)的主要用途是什么?
(3-氨苯基)环丙基甲酮主要用于合成化学中间体,特别是在药物化学领域作为原料。它还可以用于有机合成反应中,作为催化剂或反应物。
如何储存亚胺菌(CAS号:136470-79-6)?
亚胺菌应储存在干燥、阴凉处,避免直接暴露于光线下。建议使用密封容器储存,防止吸潮和污染。具体的储存条件应参考产品的安全数据表(MSDS)或药品说明书。
2-氯-2,2-二氟乙酰胺(CAS号:354-28-9)应用于哪些行业?
2-氯-2,2-二氟乙酰胺在医药、聚合物、传感器、半导体等领域有广泛应用。在医药领域,它作为中间体用于合成其他药物;在聚合物领域,用作聚合引发剂或稳定剂;在传感...
处理4-甲基-3-硝基-1,1-联苯(CAS号:53812-68-3)时应注意哪些实验室安全事项?
在处理4-甲基-3-硝基-1,1-联苯时,应佩戴手套、护目镜和实验室外套等个人防护装备(PPE),确保在通风橱中操作以减少吸入风险。若发生泄露,应立即使用沙子或...
(2S)-羟基(苯基)乙酸 (2R)-N-苄基-1-(4-甲氧基苯基)丙-2-胺盐(CAS号:188690-84-8)应用于哪些行业?
该化合物广泛应用于医药、聚合物和半导体行业。在医药领域,它是某些药物中间体的重要组成部分;在聚合物领域,可用作增塑剂;在半导体行业,可用于制造光刻胶。
在合成中是否有芬苯哒唑砜-D3标准品(CAS号:1228182-49-7)的替代品?
芬苯哒唑砜-D3标准品的替代品可能包括类似的苯并咪唑类化合物,如芬苯哒唑本身或其非同位素标记版本。这些替代品在结构上与芬苯哒唑砜-D3相似,但在具体应用中需进行...
2-氟-4-硝基苯乙酸(CAS号:315228-19-4)通常如何合成?
2-氟-4-硝基苯乙酸可以通过一系列化学反应合成,通常是从4-氟苯胺开始,首先进行硝化反应生成4-氟-2-硝基苯胺,然后进行乙酰化反应得到目标产物。具体的合成步...
2-氟-4-甲氧基苯乙酸(CAS号:883531-28-0)通常如何合成?
2-氟-4-甲氧基苯乙酸通常通过将4-甲氧基苯乙酸与氟化试剂(如氟化氰)反应来合成。反应通常在无水条件下进行,使用催化剂如六氟磷酸锂或四氟硼酸锂以提高选择性和产...
什么是4SC 202;4SC202(CAS号:1186222-89-8)?
4SC 202;4SC202是一种化学化合物,其化学名称为(2E)-N-(2-氨基苯基)-3-(1-{[4-(1-甲基-1H-吡唑-4-基)苯基]磺酰基}-1H...
来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.













![4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure 4-[(2,4-Dihydroxyphenyl)diazenyl]-5-hydroxy-2,7-naphthalenedisulfonic acid structure](https://cnstatic.chemtradehub.com/structs/362/3627-01-8-79ac.webp)
![(2E)-4-[(1R,2S,8R,19S,21R)-14-Hydroxy-11-isopropenyl-8,23,23-trimethyl-5-(3-methyl-2-buten-1-yl)-16,20-dioxo-3,7,22-trioxaheptacyclo[17.4.1.1~8,12~.0~2,17~.0~2,21~.0~4,15~.0~6,13~]pentacosa-4(15),5,13
,17-tetraen-21-yl]-2-methyl-2-butenoic acid structure (2E)-4-[(1R,2S,8R,19S,21R)-14-Hydroxy-11-isopropenyl-8,23,23-trimethyl-5-(3-methyl-2-buten-1-yl)-16,20-dioxo-3,7,22-trioxaheptacyclo[17.4.1.1~8,12~.0~2,17~.0~2,21~.0~4,15~.0~6,13~]pentacosa-4(15),5,13
,17-tetraen-21-yl]-2-methyl-2-butenoic acid structure](https://cnstatic.chemtradehub.com/structs/173/173867-04-4-d2d3.webp)