Ladder-type poly(benzopentalene) derivatives with tunable energy levels by “click” reaction

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发布日期 2012-01-30

DOI 10.1039/C2PY00593J

影响因子 5.582

作者

Dong Wang, Yuzhen Zhao, Hong Gao, Yan Xing, Huai Yang

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摘要

We have successfully synthesized two types of conjugated polymers, i.e., ladder-type or AB-type poly(benzopentalene) derivative macromoleculars, by Pd-catalyzed self-polycondensation. Incorporating long alkyl chains at the polymer peripheral positions, both polymers have very good solubility and high molecular weight. Thus, the detailed optical and electrochemical properties of the polymers were investigated. At the same time, it was very special that one type of conjugated polymer possessed reactive side groups which can be “clicked” by tetrathiafulvalene (TTF). The energy levels can be obviously changed by the “click” reaction. These results show that ladder-type poly(benzopentalene) derivatives containing reacted side groups are promising candidates for achieving optoelectronic applications.

期刊推荐

Journal of the Indian Institute of Science

Topics in Catalysis

Journal of Asian Natural Products Research

Chinese Journal of Chemistry

Biocatalysis and Biotransformation

NDT & E International

Cellulose

Electroanalysis

Medicinal Chemistry Research

Herald of the Russian Academy of Sciences

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Ladder-type poly(benzopentalene) derivatives with tunable energy levels by “click” reaction

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