Thiol–yne reaction of alkyne-derivatized fatty acids: biobased polyols and cytocompatibility of derived polyurethanes

文献信息

发布日期 2012-05-25

DOI 10.1039/C2PY20273E

影响因子 5.582

作者

Rodolfo J. González-Paz, Gerard Lligadas, Juan C. Ronda, Marina Galià, Virginia Cádiz

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摘要

With the goal of obtaining renewable diols and polyols for polyurethane (PU) technology, the thiol–yne coupling reaction was applied to alkyne-derivatized fatty acids derived from naturally occurring oleic and 10-undecenoic acids. The resulting monomers were then polymerized with 4,4′-methylenebis(phenylisocyanate) to produce the corresponding PUs. The chemical structures and thermal and mechanical properties of the synthesized PUs have been evaluated by FTIR and NMR spectroscopy, DSC, TGA and tensile tests respectively. Moreover, the biocompatibilities of the synthesized PUs with human osteoblast-like cell line (MG63) have also been evaluated for tissue engineering purposes.

期刊推荐

Chemistry of Heterocyclic Compounds

AIAA Journal

Australian Journal of Chemistry

Journal of the Chinese Chemical Society

Journal of the American Chemical Society

Analyst

Corrosion Science

Canadian Metallurgical Quarterly

Chemical Reviews

Advances in Colloid and Interface Science

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Thiol–yne reaction of alkyne-derivatized fatty acids: biobased polyols and cytocompatibility of derived polyurethanes

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Polymer Chemistry

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