Single bubble perturbation in cavitation proximity of solid glass: hot spot versus distance

文献信息

发布日期 2013-08-21
DOI 10.1039/C3CP52850B
影响因子 3.676
作者

Helmuth Möhwald, Kenneth Suslick


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摘要

A systematic study of the energy loss of a cavitation bubble in a close proximity of a glass surface is introduced for the first time in a low acoustic field (1.2–2.4 bar). Single bubble sonoluminescence (SBSL) is used as a tool to predict the temperature and pressure decrease of bubble (μm) versus surface distance. A glass as a model system is used to imitate the boundary conditions relevant for nano- or micromaterials. SBSL preequilibrated with 5% argon is perturbed by a glass rod with the tip (Z-perturbation) and with the long axis (X-perturbation) at a defined distance. From 2 mm to 500 μm argon-SBSL lines monotonically narrow and the effective emission temperature decreases from 9000 K to 6800 K comparable to multiple bubbles. The electron density decreases by two orders of magnitude in Z-perturbation and is by a factor of two higher in X-perturbation than the unperturbed cavitating bubble. The perturbed single bubble sonoluminescence pressure decreases from 2700 atm to 1200 atm at 2.4 bar. In water new non-SBSL SiO molecular emission lines are observed and OH emission disappears.

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DOI: 10.1039/C8OB90129E

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来源期刊

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
自引率: 10.3%
年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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