Main-chain second-order nonlinear optical polyaryleneethynylenes containing isolation chromophores: enhanced nonlinear optical properties, improved optical transparency and stability
文献信息
发布日期
2013-03-26
DOI
10.1039/C3PY00257H
影响因子
5.582
作者
Wenbo Wu, Shaohui Xin, Zhen Xu, Cheng Ye, Jingui Qin, Zhen Li
查看原文
摘要
In this paper, five nitro azo chromophore based main-chain second-order nonlinear optical (NLO) polyaryleneethynylenes are successfully prepared, in which isolation chromophore moieties (sulfonyl ones) with different concentrations were introduced to improve the poling efficiency of the resultant polymers. Thanks to the effect of the isolation chromophore, P5 exhibited the largest d33 value of 111.1 pm V−1 as well as the best thermal stability and optical transparency, indicating that the isolation chromophore moieties could alleviate the “nonlinearity-stability trade off” and “nonlinearity-transparency trade off” in the NLO area efficiently.
相关文献
Impacts of anions on the oxygen reduction reaction kinetics on platinum and palladium surfaces in alkaline solutions
Shangqian Zhu, Xiaomeng Hu, Minhua Shao
2017-02-17
Paper
DOI: 10.1039/C7CP00404D
Phase separation and physico-chemical processes at microscopic and macroscopic levels in MWCNT laden polymer blends using a unique droplet based architecture
Binita Pathak, Goutam Prasanna Kar, Suryasarathi Bose, Saptarshi Basu
2017-08-29
Paper
DOI: 10.1039/C7CP03621C
Photomanipulation of the anchoring strength using a spontaneously adsorbed layer of azo dendrimers
Hajnalka Nádasi, Ralf Stannarius, Alexey Eremin, Ken Ishikawa, Osamu Haba, Koichiro Yonetake, Hideo Takezoe, Fumito Araoka
2017-03-02
Paper
DOI: 10.1039/C6CP08461C
Water and CO (co-)adsorption on pseudomorphic Pt films on Ru(0001) – a low-temperature scanning tunneling microscopy study
Martin Schilling, Sylvain Brimaud, R. Jürgen Behm
2017-08-04
Paper
DOI: 10.1039/C7CP03961A
First principles study of oxygen molecule interaction with the graphitic active sites of a boron-doped pyrolyzed Fe–N–C catalyst
Febdian Rusydi
2017-08-15
Paper
DOI: 10.1039/C7CP02390A
A modeling study of methane hydrate decomposition in contact with the external surface of zeolites
2017-07-21
Paper
DOI: 10.1039/C7CP01985H
Temperature dependence of ion diffusion coefficients in NaCl electrolyte confined within graphene nanochannels
Jing Kong, Zheng Bo, Huachao Yang, Jinyuan Yang, Xiaorui Shuai, Jianhua Yan, Kefa Cen
2017-02-20
Paper
DOI: 10.1039/C6CP08752C
Bias induced spin transitions of spin crossover molecules: the role of charging effect
2017-02-16
Paper
DOI: 10.1039/C6CP08265C
Unifying hydrotropy under Gibbs phase rule
Seishi Shimizu
2017-05-11
Perspective
DOI: 10.1039/C7CP02132A
Membrane interactions and antimicrobial effects of layered double hydroxide nanoparticles
L. Nyström, R. Nordström, Z. P. Xu, M. Davoudi
2017-07-06
Paper
DOI: 10.1039/C7CP02701J
您可能还喜欢
化合物问答
(3-氨苯基)环丙基甲酮(CAS号：162174-75-6)的主要用途是什么？
(3-氨苯基)环丙基甲酮主要用于合成化学中间体，特别是在药物化学领域作为原料。它还可以用于有机合成反应中，作为催化剂或反应物。
162174-75-6(3-Aminophenyl)(cycl...
化合物问答
如何储存亚胺菌(CAS号：136470-79-6)？
亚胺菌应储存在干燥、阴凉处，避免直接暴露于光线下。建议使用密封容器储存，防止吸潮和污染。具体的储存条件应参考产品的安全数据表（MSDS）或药品说明书。
136470-79-6Abacavir EP Impurity...
化合物问答
2-氯-2,2-二氟乙酰胺(CAS号：354-28-9)应用于哪些行业？
2-氯-2,2-二氟乙酰胺在医药、聚合物、传感器、半导体等领域有广泛应用。在医药领域，它作为中间体用于合成其他药物；在聚合物领域，用作聚合引发剂或稳定剂；在传感...
354-28-92-Chloro-2,2-difluor...
化合物问答
处理4-甲基-3-硝基-1,1-联苯(CAS号：53812-68-3)时应注意哪些实验室安全事项？
在处理4-甲基-3-硝基-1,1-联苯时，应佩戴手套、护目镜和实验室外套等个人防护装备（PPE），确保在通风橱中操作以减少吸入风险。若发生泄露，应立即使用沙子或...
53812-68-34'-Methyl-3-nitro-1,...
化合物问答
(2S)-羟基(苯基)乙酸 (2R)-N-苄基-1-(4-甲氧基苯基)丙-2-胺盐(CAS号：188690-84-8)应用于哪些行业？
该化合物广泛应用于医药、聚合物和半导体行业。在医药领域，它是某些药物中间体的重要组成部分；在聚合物领域，可用作增塑剂；在半导体行业，可用于制造光刻胶。
188690-84-8Benzeneacetic acid, ...
化合物问答
在合成中是否有芬苯哒唑砜-D3标准品(CAS号：1228182-49-7)的替代品？
芬苯哒唑砜-D3标准品的替代品可能包括类似的苯并咪唑类化合物，如芬苯哒唑本身或其非同位素标记版本。这些替代品在结构上与芬苯哒唑砜-D3相似，但在具体应用中需进行...
1228182-49-7(~2~H_3_)Methyl [5-(...
化合物问答
2-氟-4-硝基苯乙酸(CAS号：315228-19-4)通常如何合成？
2-氟-4-硝基苯乙酸可以通过一系列化学反应合成，通常是从4-氟苯胺开始，首先进行硝化反应生成4-氟-2-硝基苯胺，然后进行乙酰化反应得到目标产物。具体的合成步...
315228-19-42-(2-fluoro-4-nitrop...
化合物问答
2-氟-4-甲氧基苯乙酸(CAS号：883531-28-0)通常如何合成？
2-氟-4-甲氧基苯乙酸通常通过将4-甲氧基苯乙酸与氟化试剂（如氟化氰）反应来合成。反应通常在无水条件下进行，使用催化剂如六氟磷酸锂或四氟硼酸锂以提高选择性和产...
883531-28-02-Fluoro-4-methoxyph...
化合物问答
什么是4SC 202;4SC202(CAS号：1186222-89-8)？
4SC 202;4SC202是一种化学化合物，其化学名称为(2E)-N-(2-氨基苯基)-3-(1-{[4-(1-甲基-1H-吡唑-4-基)苯基]磺酰基}-1H...
1186222-89-8(2E)-N-(2-Aminopheny...
132980-99-53,5-Difluorobenzamid...
来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
推荐化合物
![Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure](https://cnstatic.chemtradehub.com/structs/159/159635-46-8-8de0.webp "Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1) structure")
Benzyl spiro[indole-3,4'-piperidine]-1(2H)-carboxylate hydrochloride (1:1)
CAS号:
159635-46-8
分子式:
C20H23ClN2O2
![2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate structure](https://cnstatic.chemtradehub.com/structs/833/83345-46-4-eec2.webp "2-Methyl-2-propanyl [(2S)-1-hydroxy-3-(4-hydroxyphenyl)-2-propanyl]carbamate structure")
推荐供应商
免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联，也不处理投稿事宜。如有投稿相关咨询，请直接联系相关期刊出版商。
如发现页面信息有误，请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。