Microporous organic polymers with acetal linkages: synthesis, characterization, and gas sorption properties

文献信息

发布日期 2013-08-22

DOI 10.1039/C3PY00854A

影响因子 5.582

作者

Li-Min Zhang, Tao Wang, Bao-Hang Han

查看原文

摘要

A series of microporous organic polymers with acetal-linkages were synthesized through the condensation of multi-formyl-containing monomers with pentaerythritol, catalyzed by p-toluenesulfonic acid. This easily realized archetypal reaction has high yields and the commercially available starting materials, catalysts, and solvents make this condensation display great advantages over other methods for the construction of microporous organic polymers. The FT-IR and solid-state 13C NMR spectroscopy confirm the formation of the acetal-linkages in the obtained polymers. The highest Brunauer–Emmett–Teller specific surface area of these five microporous polymers is approaching 1000 m2 g−1. Moreover, their hydrogen and carbon dioxide uptake are also investigated. Generally, we provided a versatile method to prepare porous organic polymers efficiently with promising applications in gas adsorption.

期刊推荐

Nature Medicine

Russian Journal of Coordination Chemistry

Organic Process Research & Development

New Journal of Chemistry

Russian Journal of Applied Chemistry

Russian Chemical Bulletin

Russian Journal of General Chemistry

Current Opinion in Colloid & Interface Science

Chemistry Education Research and Practice

Journal of Saudi Chemical Society

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Microporous organic polymers with acetal linkages: synthesis, characterization, and gas sorption properties

文献信息

期刊推荐

相关文献

Mechanical properties of nonstoichiometric cubic titanium carbide TiCy

A photoelectron imaging study of the deprotonated GFP chromophore anion and RNA fluorescent tags

Induced VCD and conformational chirality in host–guest complexes of a chiral ammonium salt with crown ethers

Kinetic Monte Carlo simulations of self-organization of Ge islands on Si(001)

Crown ethers in hydrogenated graphene

Bonding analysis of water clusters using quasi-atomic orbitals

Initiation reactions in the high temperature decomposition of styrene

Effective π-electron number and symmetry perturbation effect on the two-photon absorption of oligofluorenes

Photoelectron photofragment coincidence spectroscopy of aromatic carboxylates: benzoate and p-coumarate

Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts

您可能还喜欢

如何储存1,2-环己二酮环乙缩醛(CAS号：4746-96-7)？

Ecopladib(CAS号：381683-92-7)的市场或研究趋势如何？

2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号：52538-09-7)通常如何合成？

2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号：17379-01-0)的市场或研究趋势如何？

解草嗪(CAS号：68-90-6)安全吗？

如何储存盐酸甘氨酸丁酯(CAS号：13048-99-2)？

什么是2-Iodo-N,N-dimethylbenzamide(CAS号：54616-46-5)？

如何储存2-氨基-N-环己基乙酰胺(CAS号：16817-90-6)？

5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号：959240-99-4)的市场或研究趋势如何？

2,4-二溴-6-三氟甲基嘧啶(CAS号：785778-00-9)通常如何合成？

来源期刊

Polymer Chemistry

推荐化合物

4-Methyl-3-morpholinecarboxylic acid hydrochloride (1:1)

[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate

cis-3-Amino-1-(trifluoromethyl)cyclobutanol hydrochloride (1:1)

1-[(4-Methylphenyl)sulfonyl]-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-pyrrolo[2,3-b]pyridine-5-carbonitrile

{[3-(Hexadecyloxy)propoxy](hydroxy)phosphoryl}methyl 4-methylbenzenesulfonate

推荐供应商