![[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure](https://cnstatic.chemtradehub.com/structs/100/100431-55-8-7104.webp "[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure")
A three-dimensional cross-linking supramolecular polymer stabilized by the cooperative dimerization of the viologen radical cation
文献信息
发布日期
2013-09-09
DOI
10.1039/C3PY01006F
影响因子
5.582
作者
Cen Zhou, Jia Tian, Ji-Liang Wang, Dan-Wei Zhang, Xin Zhao, Yi Liu, Zhan-Ting Li
查看原文
摘要
Simply introducing four viologen units to a tetraphenylmethane framework causes the corresponding viologen radical cation to strongly dimerize intermolecularly, with the apparent equilibrium constant being increased by at least 7600 times, which drives the tetrahedral molecule to self-assemble into a three-dimensional (3D) supramolecular architecture in water.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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