Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM: Guinness is good for SET-LRP

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发布日期 2013-09-11

DOI 10.1039/C3PY01075A

影响因子 5.582

作者

Christopher Waldron, Qiang Zhang, Zaidong Li, Vasiliki Nikolaou, Gabit Nurumbetov, Jamie Godfrey, Ronan McHale, Gokhan Yilmaz, Rajan K. Randev, Mony Girault, Kayleigh McEwan, David M. Haddleton, Martijn Droesbeke, Alice J. Haddleton, Paul Wilson, Alexandre Simula, Jennifer Collins, Danielle J. Lloyd, James A. Burns, Christopher Summers, Claudia Houben, Athina Anastasaki, Muxiu Li, C. Remzi Becer, Jenny K. Kiviaho, Nuttapol Risangud

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摘要

The controlled polymerization of N-isopropyl acrylamide (NIPAM) is reported in a range of international beers, wine, ciders and spirits utilizing Cu(0)-mediated living radical polymerization (SET-LRP). Highly active Cu(0) is first formed in situ by the rapid disproportionation of [Cu(I)(Me6-Tren)Br] in the commercial water–alcohol mixtures. Rapid, yet highly controlled, radical polymerization follows (Đ values as low as 1.05) despite the numerous chemicals of diverse functionality present in these solvents e.g. alpha acids, sugars, phenols, terpenoids, flavonoids, tannins, metallo-complexes, anethole etc. The results herein demonstrate the robust nature of the aqueous SET-LRP protocol, underlining its ability to operate efficiently in a wide range of complex chemical environments.

期刊推荐

Saudi Pharmaceutical Journal

Acta Materialia

Russian Journal of Coordination Chemistry

Crystallography Reports

Organic Process Research & Development

Journal of Peptide Science

Journal of Natural Medicines

Russian Journal of Bioorganic Chemistry

Chemistry Education Research and Practice

Russian Journal of Organic Chemistry

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Absolut “copper catalyzation perfected”; robust living polymerization of NIPAM: Guinness is good for SET-LRP

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