Synthesis of functionalized cyclic carbonate monomers using a versatile pentafluorophenyl carbonate intermediate
文献信息
Daniel P. Sanders, Daniel J. Coady, Manabu Yasumoto, Masaki Fujiwara, Haritz Sardon, James L. Hedrick
Functionalized cyclic carbonate monomers were synthesized via a two step route featuring a novel cyclic carbonate intermediate possessing a pendent activated pentafluorophenyl carbonate group (MTC-PFPC). The pentafluorophenyl carbonate of MTC-PFPC was selectively substituted with suitable nucleophiles such as alcohols, amines and thiols generating functionalized cyclic carbonates in moderate to high yield.
期刊推荐

Russian Chemical Bulletin

Current Opinion in Solid State & Materials Science

Journal of Natural Medicines

Organic Process Research & Development

Chemistry Education Research and Practice

Nature Medicine

Current Opinion in Colloid & Interface Science

Crystallography Reports

Russian Journal of Bioorganic Chemistry

Chemical Communications
相关文献
Experimental and computational investigation of the bond energy of thorium dicarbonyl cation and theoretical elucidation of its isomerization mechanism to the thermodynamically most stable isomer, thorium oxide ketenylidene cation, OTh+CCO
Arjun Kafle, P. B. Armentrout
DOI: 10.1039/D1CP04263G
Adsorption and reaction mechanisms of single and double H2O molecules on graphene surfaces with defects: a density functional theory study
Zeng Liang, Kejiang Li, Ziming Wang, Yushan Bu, Jianliang Zhang
DOI: 10.1039/D1CP02595C
Photoelectron photofragment coincidence spectroscopy of aromatic carboxylates: benzoate and p-coumarate
J. A. Gibbard, E. Castracane, A. I. Krylov, R. E. Continetti
DOI: 10.1039/D1CP02972J
Reduced-dimensional surface hopping with offline–online computations
Zachary Morrow, Hyuk-Yong Kwon, C. T. Kelley, Elena Jakubikova
DOI: 10.1039/D1CP03446D
Transient absorption spectroscopy of the electron transfer step in the photochemically activated polymerizations of N-ethylcarbazole and 9-phenylcarbazole
Georgia L. Thornton, Ryan Phelps, Andrew J. Orr-Ewing
DOI: 10.1039/D1CP03137F
How well do self-interaction corrections repair the overestimation of static polarizabilities in density functional calculations?
Sharmin Akter, Jorge A. Vargas, Kamal Sharkas, Juan E. Peralta, Koblar A. Jackson
DOI: 10.1039/D0CP06512A
Covalent photofunctionalization and electronic repair of 2H-MoS2via nitrogen incorporation
Helena Osthues, Christian Schwermann, Johann A. Preuß, Thorsten Deilmann, Rudolf Bratschitsch, Michael Rohlfing, Nikos L. Doltsinis
DOI: 10.1039/D1CP02313F
Vacancy-triggered and dopant-assisted NO electrocatalytic reduction over MoS2
Chao Wu
DOI: 10.1039/D1CP02764F
Analysis of reduced paramagnetic shifts as an effective tool in NMR spectroscopy
Igor A. Nikovskiy, Dmitry Y. Aleshin
DOI: 10.1039/D1CP04648A
Mechanistic insight into oxygen vacancy migration in SrFeO3−δ from DFT+U simulations
Musa Alaydrus
DOI: 10.1039/D1CP02452C
您可能还喜欢
如何储存1,2-环己二酮环乙缩醛(CAS号:4746-96-7)?
1,2-环己二酮环乙缩醛应储存在阴凉、干燥、通风良好的地方,避免阳光直射。建议使用密封容器保存,并保持环境温度在室温范围内,远离火源和热源。
Ecopladib(CAS号:381683-92-7)的市场或研究趋势如何?
Ecopladib作为一种新型的药物,主要应用于治疗高胆固醇等疾病。目前,市场和研究趋势显示,Ecopladib因其独特的药理作用而受到关注。随着对心血管疾病治...
2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号:52538-09-7)通常如何合成?
2,3-二甲基-3H-咪唑[4,5-c]吡啶通常通过咪唑和2,3-二甲基吡啶的缩合反应合成。具体来说,将咪唑和2,3-二甲基吡啶在适当的溶剂中进行加热或加压反应...
2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号:17379-01-0)的市场或研究趋势如何?
该化合物在药物化学和有机合成中有一定的应用。近年来,随着对新型药物化合物的需求增加,该化合物的研究趋势主要集中在探索其生物活性,尤其是其在神经系统疾病治疗中的潜...
如何储存盐酸甘氨酸丁酯(CAS号:13048-99-2)?
盐酸甘氨酸丁酯应储存在阴凉、干燥、通风良好的地方,避免阳光直射和高温环境,温度应控制在25℃以下。储存容器应密封,避免与空气中的水分和酸性物质接触,以防发生水解...
什么是2-Iodo-N,N-dimethylbenzamide(CAS号:54616-46-5)?
2-碘-N,N-二甲基苯胺是一种有机化合物,化学名为2-Iodo-N,N-dimethylbenzamide。其分子式为C<sub>9</sub>H<sub>1...
5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号:959240-99-4)的市场或研究趋势如何?
随着医药、农药和新材料领域的发展,该化合物作为关键中间体的应用日益增多。特别是在药物合成中,由于其独特的化学性质,可以用于合成多种药物分子。未来的研究趋势可能集...
2,4-二溴-6-三氟甲基嘧啶(CAS号:785778-00-9)通常如何合成?
2,4-二溴-6-三氟甲基嘧啶通常通过溴化反应合成。首先,将6-三氟甲基嘧啶与溴化剂(如液溴)在适当的溶剂(如二氯甲烷、四氢呋喃)中反应,加入适当的催化剂(如四...
来源期刊
Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.


![(2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure (2E)-3-(3-Chlorophenyl)-N-{2-[4-(methylsulfonyl)-1-piperazinyl]-2-oxoethyl}acrylamide structure](https://cnstatic.chemtradehub.com/structs/250/2505001-54-5-c1e9.webp)

