From particles to stabilizing blocks – polymerized ionic liquids in aqueous heterophase polymerization
文献信息
发布日期
2014-05-16
DOI
10.1039/C4PY00458B
影响因子
5.582
作者
Ran Yu, Klaus Tauer
查看原文
摘要
Suspensions of polyvinylimidazolium salts with long alkyl chains (polymerized ionic liquids) are a new class of reactive electrostatic stabilizers for aqueous polymer dispersions with dual functions – as a reductant in a redox initiator system and as a colloidal stabilizer. Studying the properties of di- and triblock copolymer dispersions (with N-isopropyl acryl amide and/or hydrophobic monomers) made with these reactive suspensions reveals an interesting behavior which is described as the principle of relative hydrophilicity. Following this principle, the colloid chemical behavior of the polyvinylimidazolium salt block depends on the relative hydrophilicity in comparison with the other blocks.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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