Synthesis of well-controlled graft polymers by living anionic polymerization towards exact graft polymers

文献信息

发布日期 2014-07-21
DOI 10.1039/C4PY00584H
影响因子 5.582
作者

Shotaro Ito, Raita Goseki, Takashi Ishizone


查看原文

摘要

This article reviews the synthesis of well-controlled graft polymers by living anionic polymerization towards exact graft polymers. The structure of a graft polymer is defined by the following three parameters: (1) molecular weight of the main chain, (2) molecular weight of the graft chain, and (3) placement of the graft chain. Based on these three parameters, the extent of the structural control of the graft polymers synthesized so far is described. Finally, the recently synthesized exact graft (co)polymers by stepwise iterative methodologies are introduced. In their structures, the three parameters are perfectly controlled.

相关文献

A microiterative intrinsic reaction coordinate method for large QM/MM systems

Iakov Polyak, Eliot Boulanger, Kakali Sen, Walter Thiel

2013-05-31 Paper

DOI: 10.1039/C3CP51669E

Inside front cover

Cover

DOI: 10.1039/C3CP90085A

Extending the distance range accessed with continuous wave EPR with Gd3+spin probes at high magnetic fields

Devin T. Edwards, Zhidong Ma, Daniella Goldfarb

2013-05-15 Paper

DOI: 10.1039/C3CP43787F

Iron cation catalyzed reduction of N2O by CO: gas-phase temperature dependent kinetics

Joshua J. Melko, Shaun G. Ard, Joseph A. Fournier, Jun Li, Nicholas S. Shuman, Hua Guo, Albert A. Viggiano

2013-05-31 Paper

DOI: 10.1039/C3CP50335F

Time-resolved photoelectron spectroscopy of adenine and adenosine in aqueous solution

Franziska Buchner, Hans-Hermann Ritze, Jan Lahl, Andrea Lübcke

2013-05-07 Paper

DOI: 10.1039/C3CP51057C

Observing reduction of 4-nitrobenzenthiol on gold nanoparticlesin situ using surface-enhanced Raman spectroscopy

Xiaoqian Ren, Tingting You, Li Jiang, Hongyan Zhang, Penggang Yin, Lin Guo

2013-06-18 Paper

DOI: 10.1039/C3CP51385H

Chromism based on supramolecular H-bonds

Chuanlang Zhan, Xunlei Ding, Shanlin Zhang, Xin Zhang, Huiying Liu, Lili Chen, Yishi Wu, Hongbing Fu, Shenggui He, Yan Huang, Jiannian Yao

2013-05-20 Paper

DOI: 10.1039/C3CP51268A

Highly sensitive, selective and reusable mercury(ii) ion sensor based on a ssDNA-functionalized photonic crystal film

Yuqi Zhang, Loujun Gao, Liping Wen, Liping Heng, Yanlin Song

2013-05-10 Paper

DOI: 10.1039/C3CP51324F

Back cover

Cover

DOI: 10.1039/C3CP90118A

您可能还喜欢

化合物问答

4,5-二甲基-2-硝基苯甲酸(CAS号:4315-14-4)的市场或研究趋势如何?

4,5-二甲基-2-硝基苯甲酸主要应用于制药、染料和农药等行业。由于其潜在的毒性,其市场趋势可能受到法规限制和环保考量的影响,推动了替代产品的研发。在研究领域,...

4315-14-44,5-Dimethyl-2-nitro...
化合物问答

处理直接黑22(CAS号:6473-13-8)时应注意哪些实验室安全事项?

处理直接黑22时应穿戴适当的个人防护装备(PPE),包括实验服、手套、护目镜和口罩。操作应在通风橱内进行,以避免吸入有害气体。如果发生泄漏,应立即清理,并使用大...

6473-13-82-Naphthalenesulfoni...
化合物问答

处理2,1,3-苯并噻二唑-4-基异氰酸酯(CAS号:342411-14-7)时应注意哪些实验室安全事项?

处理2,1,3-苯并噻二唑-4-基异氰酸酯时应注意以下安全事项:穿戴个人防护装备,如实验室外套、防护眼镜和手套;在通风橱中操作,确保良好的通风;保持实验室环境干...

342411-14-74-Isocyanato-2,1,3-b...
化合物问答

如何处理含有Δ-8,9-脱氢雌酮(CAS号:204077-66-7)的废料?

含有Δ-8,9-脱氢雌酮的废料需要进行适当的处理以确保环境和人体安全。首先,收集废液并存放于密封容器中,避免泄漏。其次,可以考虑将其转化为无害物质或通过专业处理...

204077-66-7Thioquinapiperifil d...
化合物问答

如何储存5-溴戊酸(CAS号:2067-33-6)?

5-溴戊酸应储存在阴凉、干燥、通风良好的环境中,避免阳光直射。建议在室温(约15-25°C)下保存,保持相对湿度低于60%。应使用密封的玻璃或塑料容器,并远离热...

2067-33-65-Bromopentanoic aci...
化合物问答

4-(甲基亚磺酰基)苯胺(CAS号:22865-62-9)应用于哪些行业?

4-(甲基亚磺酰基)苯胺在医药、聚合物和传感器等领域有一定的应用。在医药方面,它可以用作合成药物的中间体;在聚合物领域,可以作为合成特殊性能高分子材料的单体;在...

22865-62-94-Methylsulfinylanil...
化合物问答

什么是1-(2-FLUOROPHENYL)-5-METHYL-1H-PYRAZOLE-4-CARBOHYDRAZIDE(CAS号:618092-58-3)?

1-(2-氟苯基)-5-甲基-1H-吡唑-4-亚甲基肼是一种有机化合物,其分子式为C9H9FN3O。该化合物具有特定的物理化学性质,如熔点、沸点等,但具体值需查...

618092-58-31-(2-Fluorophenyl)-5...
化合物问答

Dauricumine(CAS号:345641-00-1)通常如何合成?

Dauricumine通常通过复杂的合成路线制备,涉及多个步骤,包括环化、氧化、卤化等反应。合成过程中使用了多种催化剂和试剂,例如金属催化剂、氧化剂等。产率通常...

345641-00-1(1R,1'S,5R,6'S,8'S)-...
化合物问答

5-氰基苯酞(CAS号:82104-74-3)安全吗?

5-氰基苯酞在正常使用条件下相对安全,但其具有一定的毒性,需谨慎操作。在实验或工业应用中,应采取适当的防护措施,如佩戴防护手套、护目镜和实验服,确保通风良好。误...

82104-74-31-Oxo-1,3-dihydro-2-...
化合物问答

2-Methyl-1-(phenylsulfonyl)-1H-pyrrolo[2,3-b]pyridin-5-amine(CAS号:1186502-59-9)安全吗?

该化合物在使用时需要谨慎操作。虽然其毒性和健康风险尚未完全明确,但建议在通风良好的环境中操作,并穿戴适当的个人防护装备,如手套和防护眼镜。

1186502-59-92-Methyl-1-(phenylsu...

来源期刊

Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
自引率: 7.3%
年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

推荐供应商

免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联,也不处理投稿事宜。如有投稿相关咨询,请直接联系相关期刊出版商。
如发现页面信息有误,请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。