The synthesis of microporous polymers using Tröger's base formation
文献信息
发布日期
2014-06-20
DOI
10.1039/C4PY00609G
影响因子
5.582
作者
Mariolino Carta, Richard Malpass-Evans, Matthew Croad, Yulia Rogan, Michael Lee, Ian Rose, Neil B. McKeown
查看原文
摘要
A step-growth polymerisation based on the formation of Tröger's base, performed by simple reaction of a suitable aromatic diamine monomer with dimethoxymethane in trifluoroacetic acid, provides polymers of high average molecular mass. The properties of the resulting polymers can be tailored by the choice of monomer. In particular, the Tröger's base polymerisation is highly suited to the preparation of soluble polymers of intrinsic microporosity (PIMs) due to the resulting fused-ring TB linking group, which is both highly rigid and prohibits conformational freedom.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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