Synthetic strategy for preparing chiral double-semicrystalline polyether block copolymers
文献信息
发布日期
2014-12-11
DOI
10.1039/C4PY01503G
影响因子
5.582
作者
Alaina J. McGrath, Weichao Shi, Christina G. Rodriguez, Nathaniel A. Lynd
查看原文
摘要
We report an effective strategy for the synthesis of semi-crystalline block copolyethers with well-defined architecture and stereochemistry. As an exemplary system, triblock copolymers containing either atactic (racemic) or isotactic (R or S) poly(propylene oxide) end blocks with a central poly(ethylene oxide) mid-block were prepared by anionic ring-opening procedures. Stereochemical control was achieved by an initial hydrolytic kinetic resolution of racemic terminal epoxides followed by anionic ring-opening polymerization of the enantiopure monomer feedstock. The resultant triblock copolymers were highly isotactic (meso triads [mm]% ∼ 90%) with optical microscopy, differential scanning calorimetry, wide angle X-ray scattering and small angle X-ray scattering being used to probe the impact of the isotacticity on the resultant polymer and hydrogel properties.
期刊推荐
Environmental Toxicology and Pharmacology
Journal of Enzyme inhibition and Medicinal Chemistry
Photochemical & Photobiological Sciences
Journal of Medical Biochemistry
Advanced Engineering Materials
Nature Reviews Drug Discovery
Foundations of Chemistry
CrystEngComm
Physical Chemistry Chemical Physics
Lab on a Chip
相关文献
Specific ion effects on the hydrophobic interaction of benzene self-assembled monolayers
S. Dobberschütz, M. Rimmen, T. Hassenkam, M. P. Andersson, S. L. S. Stipp
2015-07-22
Paper
DOI: 10.1039/C5CP01803J
Particle size dependence of the surface-enhanced Raman scattering properties of densely arranged two-dimensional assemblies of Au(core)–Ag(shell) nanospheres
Kosuke Sugawa, Tsuyoshi Akiyama, Yoshimasa Tanoue, Takashi Harumoto, Sayaka Yanagida, Atsuo Yasumori, Shohei Tomita, Joe Otsuki
2014-12-19
Paper
DOI: 10.1039/C4CP05058D
Structural characterization of gas-phase cysteine and cysteine methyl ester complexes with zinc and cadmium dications by infrared multiple photon dissociation spectroscopy
Rebecca A. Coates, Christopher P. McNary, Georgia C. Boles, Giel Berden, P. B. Armentrout
2015-04-09
Paper
DOI: 10.1039/C5CP01500F
Mesoscopic modeling of structural and thermodynamic properties of fluids confined by rough surfaces
Ketzasmin A. Terrón-Mejía, Roberto López-Rendón, Armando Gama Goicochea
2015-09-09
Paper
DOI: 10.1039/C5CP03823E
In situ Raman and surface-enhanced Raman spectroscopy on working electrodes: spectroelectrochemical characterization of water oxidation electrocatalysts
Xavier Sala
2015-02-09
Perspective
DOI: 10.1039/C4CP05053C
Surface-enhanced IR absorption spectroscopy of the KcsA potassium channel upon application of an electric field
Akira Yamakata, Hirofumi Shimizu, Shigetoshi Oiki
2015-06-23
Perspective
DOI: 10.1039/C5CP02681D
CTAB micelles assisted rGO–AgNP hybrids for SERS detection of polycyclic aromatic hydrocarbons
Meng Jiang, Zhijiang Qian, Xufeng Zhou, Xing Xin, Jinghua Wu, Chao Chen, Gongjun Zhang, Gaojie Xu, Yuchuan Cheng
2014-11-28
Paper
DOI: 10.1039/C4CP04888A
Why LiFePO4 is a safe battery electrode: Coulomb repulsion induced electron-state reshuffling upon lithiation
Bernardo Barbiellini, Hasnain Hafiz, Susmita Basak, Jun Liu, Thomas Richardson, Guojiun Shu, Fangcheng Chou, Tsu-Chien Weng, Dennis Nordlund, Dimosthenis Sokaras, Brian Moritz, Thomas P. Devereaux, Ruimin Qiao, Yi-De Chuang, Arun Bansil, Zahid Hussain, Wanli Yang
2015-09-03
Paper
DOI: 10.1039/C5CP04739K
Theoretical study on interactions of fluorinated organomercurials with arene and gold fragments
Sebastián Miranda-Rojas
2015-09-14
Paper
DOI: 10.1039/C5CP04503G
Diffusion in Li2O studied by non-equilibrium molecular dynamics for 873 < T/K < 1603
Alexander D. Mulliner, Philippe C. Aeberhard, Peter D. Battle
2015-07-29
Paper
DOI: 10.1039/C5CP02628H
您可能还喜欢
化合物问答
什么是3-表南美楝属二醇(CAS号：19942-04-2)？
3-表南美楝属二醇是一种具有特定立体化学结构的化合物，其分子式为C31H52O2，属于甾醇类化合物。它具有光学活性，是一种复杂的有机分子，主要存在于一些植物中。
19942-04-2(3S,5R,8R,9R,10R,13R...
化合物问答
3-羧基-5-碘苯甲酸甲酯(CAS号：50765-22-5)应用于哪些行业？
3-羧基-5-碘苯甲酸甲酯主要应用于医药行业，作为合成某些药物中间体的重要原料。此外，它还可能用于聚合物的改性、传感器的制备以及半导体材料的制备等领域。
50765-22-5Methyl 3-hydroxy-5-i...
化合物问答
什么是3-Bromoindolin-2-one(CAS号：22942-87-6)？
3-Bromoindolin-2-one是一种含有溴代基团的吲哚酮衍生物，分子式为C9H7BrNO。它是一种无色固体，具有一定的挥发性，熔点为158-159°C...
22942-87-63-Bromoindolin-2-one
化合物问答
如何处理含有L-Lysyl-L-phenylalanyl-L-isoleucylglycyl-L-leucyl-L-methioninamide(CAS号：2990-43-4)的废料？
对于含有该化合物的废液，应先进行中和处理，然后根据其毒性和活性选择合适的处置方法。可以考虑焚烧处理或由专业的化学品废物处理公司进行无害化处理。处理过程中需注意环...
2990-43-4L-Lysyl-L-phenylalan...
化合物问答
ANGIOTENSIN 1/2 + A (2 - 8)(CAS号：51833-76-2)的物理化学性质是什么？
ANGIOTENSIN 1/2 + A (2 - 8)是一种蛋白质类化合物，具有典型的蛋白质性质。它的分子量约为5900 Da。该化合物在水中具有一定的溶解性，...
51833-76-2ANGIOTENSIN 1/2 + A ...
化合物问答
如何储存2-甲基硫代嘧啶-5-硼酸频那酯(CAS号：940284-18-4)？
应将该化合物存放在阴凉干燥、通风良好的地方，避免阳光直射。建议将化合物密封保存在避光的、干燥的容器中，远离火源和高温环境。
940284-18-42-(Methylthio)-5-(4,...
化合物问答
什么是苏丹红IV氘代物 标准品(CAS号：1014689-18-9)？
苏丹红IV氘代物 标准品是一种含有氘代标记的苏丹红IV化合物，是一种用于化合物分析、结构确证以及代谢研究的标准物质。
1014689-18-91-[(E)-{2-Methyl-4-[...
化合物问答
(+)-2-Amino-6-propionamido-d3-tetrahydrobenzothiazole(CAS号：1217680-69-7)适用哪些法规指南？
该化合物需要遵循《全球化学品统一分类和标签制度》（GHS）中的分类和标签要求，具体分类需依据其毒性和物理化学性质。此外，还需要符合《欧盟化学品注册、评估、授权和...
1217680-69-7(+)-2-Amino-6-propio...
化合物问答
如何储存2-氨基-2-(2-吡啶)乙酸乙酯(CAS号：55243-15-7)？
2-氨基-2-(2-吡啶)乙酸乙酯应储存于阴凉、干燥、通风良好的环境中，避免高温和光照。应使用密封容器储存，并远离易燃物、氧化剂和其他危险化学品。
55243-15-7Ethyl 2-amino-2-(pyr...
化合物问答
3-羟基-4-甲氧基吡啶-2-羧酸(CAS号：210300-09-7)的主要用途是什么？
3-羟基-4-甲氧基吡啶-2-羧酸主要用于合成其他有机化合物，如药物合成、农药合成和染料合成等。此外，它还可用作中间体和试剂，在化学研究领域也有一定的应用。
210300-09-73-Hydroxy-4-methoxy-...
来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
推荐化合物
推荐供应商
免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联，也不处理投稿事宜。如有投稿相关咨询，请直接联系相关期刊出版商。
如发现页面信息有误，请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。