![Ethyl ({[(2-methyl-2-propanyl)oxy]carbonyl}amino)(2-pyridinyl)acetate structure](https://cnstatic.chemtradehub.com/structs/313/313490-90-3-dd15.webp "Ethyl ({[(2-methyl-2-propanyl)oxy]carbonyl}amino)(2-pyridinyl)acetate structure")
Ethyl ({[(2-methyl-2-propanyl)oxy]carbonyl}amino)(2-pyridinyl)acetate
CAS号:
313490-90-3
分子式:
C14H20N2O4
CO-enabled rhenium hydride catalyst for directed C(sp2)–H bond alkylation with olefins‡
文献信息
发布日期
2015-02-03
DOI
10.1039/C4QO00329B
影响因子
5.281
作者
Hongming Jin, Zhengbo Zhu, Ning Jin, Jin Xie, Yixiang Cheng
查看原文
摘要
We report the first example of CO-enabled rhenium hydride complex-catalyzed inter- and intra-molecular hydroarylation of activated alkenes, with a broad reaction scope. α,β-Unsaturated ketones, esters and amides are all suitable for this transformation. It affords a novel and convenient protocol to construct 3-methylindolones. In addition, mechanistic investigations suggest that a rhenium carbonyl hydride species may act as a key intermediate.
期刊推荐
Russian Chemical Reviews
Proceedings of the National Academy of Sciences of the United States of America
Pharmacological Reviews
Journal of Organometallic Chemistry
Organic Preparations and Procedures International
Journal of Heterocyclic Chemistry
Nature
Kinetics and Catalysis
Science Progress
Fibre Chemistry
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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