Optimization of the surface properties of nanostructured Ni–W alloys on steel by a mixed silane layer
文献信息
M. P. Quiroga Argañaraz, J. M. Ramallo-López, G. Benítez, A. Rubert, E. D. Prieto, L. M. Gassa, R. C. Salvarezza, M. E. Vela
Ni–W nanostructured coatings electrodeposited on steel by galvanostatic pulses were functionalized by tetraethoxysilane (TEOS) and octadecyltrichlorosilane (OTS) in a two-step procedure. A silica-rich layer is formed by the reaction of TEOS with the metal coating surface oxides, which allows a further reaction with OTS forming a hydrocarbon–silica outer network. This mixed silane layer provides hydrophobicity and improves the corrosion behavior of the Ni–W surface coatings without modifying their excellent mechanical properties.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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