Post-polymerization modification of poly(vinyl ether)s: a Ru-catalyzed oxidative synthesis of poly(vinyl ester)s and poly(propenyl ester)s
文献信息
Di Liu
Poly(vinyl ester)s were readily prepared via a ruthenium catalyzed C–H oxidation of the corresponding poly(vinyl ether)s under mild conditions. The transformations were efficient and in many cases proceeded without significant chain cleavage. The method was also successfully used to prepare high molecular weight poly(propenyl ester) for the first time as well as a polyester with a relatively high content (>50%) of γ-butyrolactone repeat unit from poly(tetrahydrofuran). The polymeric products were characterized via FT-IR spectroscopy, NMR spectroscopy, gel permeation chromatography, and other techniques.
期刊推荐

Chemistry of Heterocyclic Compounds

Chemical & Pharmaceutical Bulletin

Anti-Corrosion Methods and Materials

Chemistry of Natural Compounds

Canadian Metallurgical Quarterly

Advances in Colloid and Interface Science

Journal of the American Chemical Society

Bulletin of the Chemical Society of Japan

Analyst

Accounts of Chemical Research
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Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.



![[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure [(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate structure](https://cnstatic.chemtradehub.com/structs/100/100431-55-8-7104.webp)
