Continuous flow SET-LRP in the presence of P(VDF-co-CTFE) as macroinitiator in a copper tubular reactor

文献信息

发布日期 2015-11-09

DOI 10.1039/C5PY01728A

影响因子 5.582

作者

Ning Zhu, Xin Hu, Yajun Zhang, Kai Zhang, Zhenjiang Li, Kai Guo

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摘要

A green, highly effective and energy-saving route to the grafting modification of polymers was developed via continuous flow single electron transfer living radical polymerization (SET-LRP) in a copper tubular reactor. Polymerizations of methyl methacrylate and acrylonitrile in the presence of poly(vinylidene fluoride-co-chlorotrifluoroethylene) as the macroinitiator were used as model investigation systems. Significant benefits were achieved in the continuous flow mode compared to a batch reactor including diminished inconsistent induction times and suppressed “hot spot” effects. Furthermore, accelerated reaction rates, lower reaction temperatures and decreased ligand feed concentrations were observed by utilizing the copper tubular reactor. The structures of the modified P(VDF-co-CTFE) graft copolymers were characterized using 1H NMR, 19F NMR, FT-IR, and SEC.

期刊推荐

Advances in Colloid and Interface Science

Accounts of Chemical Research

Bulletin of the Chemical Society of Japan

Doklady Chemistry

Carbon

Anti-Corrosion Methods and Materials

Chemical Reviews

Chemistry of Natural Compounds

Ferroelectrics

Chemistry of Heterocyclic Compounds

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Continuous flow SET-LRP in the presence of P(VDF-co-CTFE) as macroinitiator in a copper tubular reactor

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