Vacuum ultraviolet photodissociation of hydrogen bromide
文献信息
Yvonne Dorenkamp, Shengrui Yu, Alec M. Wodtke, Dongxu Dai, Kaijun Yuan, Xueming Yang
Photodissociation dynamics of HBr at a series of photolysis wavelengths in the range of 123.90–125.90 nm and at around 137.0 nm have been studied using the H atom Rydberg “tagging” time-of-flight technique. The branching fractions between the channels forming ground Br(2P3/2) and spin–orbit excited Br(2P1/2) atoms together with the angular distributions of the products corresponding to these two channels have been measured. The photolysis wavelengths in this work excited the HBr molecule from the ground state X 1Σ+ to various Rydberg states and the V 1Σ+ ion-pair valence state. Predissociation via these states displays rich behavior, indicating the influence of the nature of initially excited states and the coupling to other bound or repulsive states on the predissociation dynamics.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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