Well-defined (co)polypeptides bearing pendant alkyne groups

文献信息

发布日期 2016-03-18

DOI 10.1039/C6PY00365F

影响因子 5.582

作者

Yves Gnanou

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摘要

A novel metal-free strategy, using hydrogen-bonding catalytic ring opening polymerization of alkyne-functionalized N-carboxy anhydrites of α-amino acids, was developed for the synthesis of well-defined polypeptides bearing pendant alkyne groups. This method provides an efficient way to synthesize novel alkyne-functionalized homopolypeptides (A) and copolypeptides, such as AB diblock (B: non-functionalized), ABA triblock and star-AB diblock, as well as linear and star random copolypeptides, which are precursors of a plethora of complex macromolecular architectures by click chemistry.

期刊推荐

Chemistry Education Research and Practice

Current Opinion in Solid State & Materials Science

Journal of Peptide Science

Organic Process Research & Development

Crystallography Reports

Russian Journal of Bioorganic Chemistry

Chemical Communications

New Journal of Chemistry

Russian Journal of Applied Chemistry

Journal of Natural Medicines

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Well-defined (co)polypeptides bearing pendant alkyne groups

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