One-pot synthesis and postpolymerization functionalization of cyclic carbonate/epoxide-difunctional polycarbonates prepared by regioselective diepoxide/CO2 copolymerization

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发布日期 2016-05-30

DOI 10.1039/C6PY00563B

影响因子 5.582

作者

Bing Han, Li Zhang, Hongye Zhang, Huining Ding, Binyuan Liu, Xianhong Wang

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摘要

Novel aliphatic polycarbonates with a tunable number of cyclic carbonate and epoxide dual functional groups were synthesized via an (ONSO)CrCl-mediated copolymerization of 4-vinyl-1-cyclohexene diepoxide with carbon dioxide in one pot. The resulting difunctional polycarbonates with high Tg afforded a versatile platform for the postpolymerization functionalization.

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Chemistry Education Research and Practice

Organic Process Research & Development

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Saudi Pharmaceutical Journal

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Journal of Natural Medicines

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

One-pot synthesis and postpolymerization functionalization of cyclic carbonate/epoxide-difunctional polycarbonates prepared by regioselective diepoxide/CO2 copolymerization

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