Aqueous RAFT at pH zero: enabling controlled polymerization of unprotected acyl hydrazide methacrylamides

文献信息

发布日期 2016-10-17

DOI 10.1039/C6PY01563H

影响因子 5.582

作者

Emily A. Hoff, Brooks A. Abel, Chase A. Tretbar, Charles L. McCormick, Derek L. Patton

查看原文

摘要

We report aqueous RAFT polymerization at pH = 0 mediated by a novel imidazolium-containing chain transfer agent. In 1 M HCl, unprecedented controlled polymerization and chain-extension of unprotected acyl hydrazide methacrylamides is achieved enabling the synthesis of well-defined acyl hydrazide functionalized polymer scaffolds of interest for dynamic covalent and bioconjugation strategies.

期刊推荐

Nature Reviews Drug Discovery

Faraday Discussions

Mini-Reviews in Medicinal Chemistry

European Journal of Organic Chemistry

Lab on a Chip

Journal of Enzyme inhibition and Medicinal Chemistry

Foundations of Chemistry

Green Chemistry

Physical Chemistry Chemical Physics

Environmental Toxicology and Pharmacology

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Aqueous RAFT at pH zero: enabling controlled polymerization of unprotected acyl hydrazide methacrylamides

文献信息

期刊推荐

相关文献

Versatile procedure for site-specific grafting of polymer brushes on patchy particles via atom transfer radical polymerization (ATRP)

Benzobisthiadiazole-alt-bithiazole copolymers with deep HOMO levels for good-performance field-effect transistors with air stability and a high on/off ratio

One-pot two polymers: ABB′ melt polycondensation for linear polyesters and hyperbranched poly(ester-urethane)s based on natural l-amino acids

Synthesis, characterization and device optimisation of new poly(benzo[1,2-b:4,5-b′]dithiophene-alt-thieno[3,4-d]thiazole) derivatives for solar cell applications

A dual stimuli responsive fluorescent probe carrier from a double hydrophilic block copolymer capped with β-cyclodextrin

Thermo- and pH-sensitive shape memory polyurethane containing carboxyl groups

Self-assembly of cyclic polymers

A study on tunable AIE (AIEE) of boron ketoiminate-based conjugated polymers for live cell imaging

Self-assembly of amphiphilic macrocycles containing polymeric liquid crystal grafts in solution

Activation of ice recrystallization inhibition activity of poly(vinyl alcohol) using a supramolecular trigger

您可能还喜欢

如何储存1,2-环己二酮环乙缩醛(CAS号：4746-96-7)？

Ecopladib(CAS号：381683-92-7)的市场或研究趋势如何？

2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号：52538-09-7)通常如何合成？

2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号：17379-01-0)的市场或研究趋势如何？

解草嗪(CAS号：68-90-6)安全吗？

如何储存盐酸甘氨酸丁酯(CAS号：13048-99-2)？

什么是2-Iodo-N,N-dimethylbenzamide(CAS号：54616-46-5)？

如何储存2-氨基-N-环己基乙酰胺(CAS号：16817-90-6)？

5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号：959240-99-4)的市场或研究趋势如何？

2,4-二溴-6-三氟甲基嘧啶(CAS号：785778-00-9)通常如何合成？

来源期刊

Polymer Chemistry

推荐化合物

Methyl 2-hydroxydodecanoate

Ramipril Acyl-|A-D-glucuronide, ~ 80% By HPLC

N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide

[(1S,2S,3R,4S,7R,9S,10S,12R,15S)-4,12-Diacetyloxy-15-[(2R,3S)-3-benzamido-3-phenyl-2-(2,2,2-trichloroethoxycarbonyloxy)propanoyl]oxy-1,9-dihydroxy-10,14,17,17-tetramethyl-11-oxo-6-oxatetracyclo[11.3.1.03,10.04,7]heptadec-13-en-2-yl] benzoate

6-Bromo-3,4-dihydro-2H-1,4-benzoxazine hydrochloride (1:1)

推荐供应商