Efficient synthesis of (S,R)-Bn-Yanphos and Rh/(S,R)-Bn-Yanphos catalyzed asymmetric hydroformylation of vinyl heteroarenes
文献信息
发布日期
2016-12-06
DOI
10.1039/C6QO00641H
影响因子
5.281
作者
Biao Wei, Caiyou Chen, Cai You, Hui Lv
查看原文
摘要
A concise and efficient synthesis of (S,R)-Bn-Yanphos on a gram scale has been developed. When (S,R)-Bn-Yanphos was employed in Rh-catalyzed asymmetric hydroformylation of vinyl heteroarenes and allyl-1H-indole, it exhibited excellent catalytic activity, affording chiral heteroaryl aldehydes in good yields with high regio- and enantioselectivities (up to 96% ee).
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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