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Inducing chemical reactivity on specific sites of a molecule using the Coulomb interaction exerted by a low energy electron
文献信息
发布日期
2018-01-17
DOI
10.1039/C7CP08496J
影响因子
3.676
作者
Y. Sajeev
查看原文
摘要
Remarkable site-specificity in the resonant attachment of low energy electrons (LEEs) to molecular targets is proposed as an efficient method for inducing chemical reactivity on specific sites of molecules. The Coulomb interaction between the attached electron and the most polarizable molecular electrons localized on the attached site is the reason for site-specific chemical reactivity. The Coulombically induced site-specific chemical reactivity is best illustrated by the LEE induced chemical transformation of a weakly bound molecular complex into a strong covalent adduct. The chemical transformation occurs due to the Coulombically induced nucleophilicity on a specific molecular moiety in the complex. A simple strategy for inducing site-specific chemical reactivity using a LEE may find new avenues in chemical synthesis.
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来源期刊
Physical Chemistry Chemical Physics
CiteScore:
5.5
自引率:
10.3%
年发文量:
3036
Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
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