A nickel catalyzed acceptorless dehydrogenative approach to quinolines
文献信息
Seuli Parua, Rina Sikari, Suman Sinha, Siuli Das, Gargi Chakraborty, Nanda D. Paul
A general, efficient and environmentally benign, one-step synthesis of substituted quinoline derivatives was achieved by acceptorless dehydrogenative coupling of o-aminobenzylalcohols with ketones and secondary alcohols catalyzed by a cheap, earth abundant and easy to prepare nickel catalyst [Ni(MeTAA)], featuring a tetraaza macrocyclic ligand (tetramethyltetraaza[14]annulene (MeTAA)). A wide variety of substituted quinolines were synthesized in high yields starting from readily available o-aminobenzylalcohols and ketones or secondary alcohols. A few controlled reactions were carried out to establish the acceptorless dehydrogenative nature of the reactions.
期刊推荐
相关文献
Structure, reactivity, photoactivity and stability of Ti–O based materials: a theoretical comparison
Yun Wang, Tao Sun, Dongjiang Yang, Hongwei Liu, Haimin Zhang, Xiangdong Yao, Huijun Zhao
DOI: 10.1039/C2CP23143C
On the analyses of fluorescence depolarisation data in the presence of electronic energy migration. Part I: Theory and general description
Oleg Opanasyuk, Lennart B.-Å. Johansson
DOI: 10.1039/C1CP22483B
Interfacial electron transfer dynamics in dye-modified graphene oxide nanosheets studied by single-molecule fluorescence spectroscopy
Takashi Tachikawa, Shi-Cong Cui, Mamoru Fujitsuka, Tetsuro Majima
DOI: 10.1039/C2CP23317G
The electric field as a novel switch for uptake/release of hydrogen for storage in nitrogen doped graphene
Z. M. Ao, F. M. Peeters, S. Li
DOI: 10.1039/C1CP23153G
Laser pulse trains for controlling excited state dynamics of adenine in water
Jens Petersen, Matthias Wohlgemuth, Bernhard Sellner, Roland Mitrić
DOI: 10.1039/C2CP24002E
Matrix isolation ESR spectroscopy and quantum chemical calculations on 5-methylhexa-1,2,4-triene-1,3-diyl, a highly delocalized triplet “hybrid” carbene
Eugenii Ya. Misochko, Alexander V. Akimov, Denis V. Korchagin, Artem A. Masitov, Konstantin N. Shavrin
DOI: 10.1039/C2CP22853J
Finite-element simulations of the influence of pore wall adsorption on cyclic voltammetry of ion transfer across a liquid–liquid interface formed at a micropore
Jonathan S. Ellis, Jörg Strutwolf, Damien W. M. Arrigan
DOI: 10.1039/C2CP23052F
Influence of a charged graphene surface on the orientation and conformation of covalently attached oligonucleotides: a molecular dynamics study
O. Kroutil, M. Předota, F. Lankaš, M. Šíp
DOI: 10.1039/C2CP23540D
Losartan's affinity to fluid bilayers modulates lipid–cholesterol interactions
P. Zoumpoulakis, G. Pabst, T. Mavromoustakos, M. Rappolt
DOI: 10.1039/C2CP40134G
您可能还喜欢
2-Bromo-4-chloro-1-(difluoromethyl)benzene(CAS号:1261476-50-9)的市场或研究趋势如何?
随着环保要求的提高和安全意识的增强,该化合物的研究和应用趋势正逐渐转向更安全、更环境友好的替代品。市场关注点主要集中在开发新型合成方法和绿色化学路径,以减少有害...
如何处理含有2,9 - 二苯基-1,10 - 菲罗啉(CAS号:25677-69-4)的废料?
处理含有2,9 - 二苯基 - 1,10 - 菲罗啉的废料时,应先将其收集在适当的容器中,避免与其他化学品混合。随后,可以通过水解或氧化等方法进行处理,直至达到...
处理(6-氯-吡嗪-3-基)-(4-乙基-哌嗪-1-基)-甲酮(CAS号:1178836-15-1)时应注意哪些实验室安全事项?
处理(6-氯-吡嗪-3-基)-(4-乙基-哌嗪-1-基)-甲酮时,应穿戴适当的个人防护装备(PPE),包括手套、护目镜和实验室外套。在通风橱中操作以确保良好的通...
处理(R)-2-氯-1-(2,4-二氯苯基)乙醇(CAS号:114446-57-0)时应注意哪些实验室安全事项?
在处理(R)-2-氯-1-(2,4-二氯苯基)乙醇时,应佩戴防护眼镜、实验室外套和手套,确保通风橱开启以减少接触和吸入的风险。避免直接接触皮肤和眼睛。处理过程中...
在合成中是否有3-氯-6-(3-氯哌啶-1-基)吡嗪(CAS号:1185310-37-5)的替代品?
可考虑使用类似结构的化合物作为替代品,如3-氯-6-(哌啶-1-基)吡嗪或3-氯-6-(2-氯哌啶-1-基)吡嗪,这些化合物在结构上与目标化合物相似,可能具有相...
苯并三氮唑-5-甲酸乙酯(CAS号:73605-91-1)通常如何合成?
该化合物可以通过乙酸乙酯与5-溴-1H-苯并三氮唑的反应合成,通常在无水条件下进行。合成过程中,需要使用适当的溶剂如乙酸乙酯,并在适当的温度下反应。该反应具有较...
什么是一水硫酸镁(CAS号:14168-73-1)?
一水硫酸镁是一种无机化合物,化学式为MgSO₄·H₂O,CAS号为14168-73-1。它由镁离子、硫酸根离子和一个结晶水分子组成,通常呈现为白色粉末或颗粒状固...
氘代-1,3-二氯-2-丙醇(CAS号:1173020-20-6)应用于哪些行业?
氘代-1,3-二氯-2-丙醇主要应用于医药和有机合成领域,作为研究化合物的氘代替代品,用于标记和追踪反应过程。此外,在聚合物和半导体生产中也有一定的应用潜力。
如何储存氰乙酸环己酯(CAS号:52688-11-6)?
氰乙酸环己酯应储存在阴凉、干燥、通风良好的环境中,远离火源和热源,防止阳光直射。储存容器应密封良好,避免与空气接触,防止发生不必要的反应。
2-碘-4-硝基苯胺(CAS号:6293-83-0)的市场或研究趋势如何?
目前,2-碘-4-硝基苯胺在医药和农药领域有一定的研究和应用,尤其是在开发新型药物和农药产品方面。然而,由于其潜在的环境和健康风险,行业正趋向于寻找更为安全和环...
来源期刊
Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.













![Bis(N,N''-dimethylpiperazine)tetra[copper(I) iodide] structure Bis(N,N''-dimethylpiperazine)tetra[copper(I) iodide] structure](https://cnstatic.chemtradehub.com/structs/140/1401708-91-5-2b86.webp)
amine structure [(2-chlorophenyl)methyl](ethyl)amine structure](https://cnstatic.chemtradehub.com/structs/629/62924-61-2-0728.webp)