Hyperbranched polysiloxane with highly constrained rings and the effect of the attached arms on the assembly behavior
文献信息
发布日期
2017-10-06
DOI
10.1039/C7PY01177F
影响因子
5.582
作者
Chunyan Wu, Chunhua Hu, Yuzhou Liu
查看原文
摘要
The preparation of hyperbranched polymers with incompatible arms and narrow molecular dispersity is appealing but is hindered by the lack of control of intramolecular cyclization, which usually leads to the formation of inert loops. We succeeded in deliberately directing the intramolecular cyclization into the formation of highly constrained and thus reactive rings, which are then used for arm attachment. In this way, a simple and efficient synthesis of a hyperbranched tri-block polymer with incompatible arms is realized and its potential application in self-assembly is demonstrated with the formation of interesting giant toroid structures.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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