Force-induced cleavage of a labile bond for enhanced mechanochemical crosslinking
文献信息
发布日期
2017-10-03
DOI
10.1039/C7PY01431G
影响因子
5.582
作者
Shu Wang, Grant A. Knappe, Norman J. Wagner
查看原文
摘要
We introduce a simple, yet powerful approach towards force-induced healing polymers. While most synthetic polymers fail in response to stress and have no recovery mechanism, we demonstrate that polymers containing a thiocarbonylthio group exhibit amplified mechanochemical activity. In the presence of a crosslinker, the radicals generated from homolytic cleavage are exploited to trigger a ‘healing’ response within minutes.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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