2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride
CAS号:
1329799-67-8
分子式:
C7H2ClD6NO2
Synthetic strategies towards mycolactone A/B, an exotoxin secreted by Mycobacterium ulcerans
文献信息
发布日期
2017-08-28
DOI
10.1039/C7QO00608J
影响因子
5.281
作者
Sarah Saint-Auret, Hajer Abdelkafi, Didier Le Nouen, Philippe Bisseret, Nicolas Blanchard
查看原文
摘要
Mycolactone A/B, a complex polyketidic macrolide secreted by Mycobacterium ulcerans, has been synthesized using catalytic and/or asymmetric reactions. Several palladium-catalyzed reactions were investigated for forging key σ-bonds as well as a particularly challenging hydroboration reaction of a functionalized and sterically demanding 1,1-disubstituted exo-alkene. The full account of these investigations is discussed.
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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