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A noble metal-free photocatalytic system based on a novel cobalt tetrapyridyl catalyst for hydrogen production in fully aqueous medium
文献信息
发布日期
2017-12-07
DOI
10.1039/C7SE00428A
影响因子
6.367
作者
N. Queyriaux, E. Giannoudis, C. D. Windle, S. Roy, J. Pécaut, A. G. Coutsolelos, V. Artero, M. Chavarot-Kerlidou
查看原文
摘要
The new cobalt tetrapyridyl complex 1(BF4)2 was characterized and assessed for hydrogen production in fully aqueous solution. Mechanistic information was gained thanks to a fast screening method, using chemical reductants and a Clark microelectrode. Optimal hydrogen production (443 TONs – 3 mL of H2) was achieved under visible light-driven conditions, in the presence of a noble metal-free photosensitizer, the water soluble porphyrin 2Cl4, and the ascorbate/tris-(2-carboxyethyl)phosphine (TCEP) sacrificial electron donor system.
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