A simple functionalized silica microsphere for fast PETN vapor detection based on fluorescence color changes via a catalyzed oxidation process
文献信息
Dehai Mu, Pengran Guo
In this work, we report a new fluorescent material for pentaerythritol tetranitrate (PETN) vapor detection. A series of fluorene substituted vinyl-SiO microspheres with different ratios has been designed and easily synthesized. Sensing films on quartz plates were obtained by a solid phase transfer method. With a specific diameter of SiO and a specific density of surrounding fluorene, the microspheres performed a rapid fluorescence color change via oxidation with highly selective PETN catalysis. The emission peak at 355 nm was rapidly quenched while an enhancement at 525 nm appeared under exposure to PETN saturated vapor. Herein, we present this fluorescent silica nanoparticle as an excellent sensing material towards vapor phase PETN, making contributions to many fields such as public security and military use.
相关文献
Oxide–organic heterostructures: a case study of charge transfer disturbance at a SnO2–copper phthalocyanine buried interface
Lucyna Grządziel, Paulina Powroźnik, Monika Kwoka, Julian Rechmann
DOI: 10.1039/C8CP01976B
Reductive defluorination of graphite monofluoride by weak, non-nucleophilic reductants reveals low-lying electron-accepting sites
Yijun Liu, Benjamin W. Noffke, Xinfeng Gao, Yaroslav Lozovyj, Yongzhu Fu, Krishnan Raghavachari, Allen R. Siedle, Liang-shi Li
DOI: 10.1039/C8CP00384J
Emergent property of high hardness for C-rich ruthenium carbides: partial covalent Ru–Ru bonds
Chunhong Xu, Hongyu Yu, Bao Kuo, Shuailing Ma, Xuehui Xiao, Da Li, Defang Duan, Xilian Jin, Bingbing Liu, Tian Cui
DOI: 10.1039/C7CP07835H
Understanding the ionic conductivity maximum in doped ceria: trapping and blocking
Julius Koettgen, Philipp Hein, Benjamin O. H. Grope
DOI: 10.1039/C7CP08535D
First-principles method for calculating the rate constants of internal-conversion and intersystem-crossing transitions
V. N. Cherepanov, D. Sundholm
DOI: 10.1039/C7CP08703A
Chirality switching of the self-assembled CuPc domains induced by electric field
Ya-Li Wang, Kai Sun, Yu-Bing Tu, Min-Long Tao, Zheng-Bo Xie, Hong-Kuan Yuan, Zu-Hong Xiong, Jun-Zhong Wang
DOI: 10.1039/C7CP08279G
Sum-frequency vibrational spectroscopy of limonene chiral liquids due to the nonadiabatic effect
Ren-hui Zheng, Wen-mei Wei, Meng Xu, Qiang Shi
DOI: 10.1039/C7CP08473K
Electron injection study of photoexcitation effects on supported subnanometer Pt clusters for CO2 photoreduction
Chi-Ta Yang, Brandon C. Wood, Venkat R. Bhethanabotla, Babu Joseph
DOI: 10.1039/C8CP00619A
A first-principles study of stability of surface confined mixed metal oxides with corundum structure (Fe2O3, Cr2O3, V2O3)
A. S. M. Jonayat, Alan Kramer, Luca Bignardi, Paolo Lacovig, Silvano Lizzit, Matthias Batzill, Michael J. Janik
DOI: 10.1039/C8CP00154E
Anharmonic lattice dynamics of bcc sodium under high pressures
Shasha Li, Chen Wang, Yue Chen
DOI: 10.1039/C8CP02086H
您可能还喜欢
什么是2-Bromo-1-(pyrimidin-2-yl)ethanone hydrobromide(CAS号:1588441-02-4)?
2-Bromo-1-(pyrimidin-2-yl)ethanone hydrobromide是一种有机化合物,分子式为C6H5Br2N2O2。它是一种溴代化合...
在合成中是否有1-正-丁基-3-甲基咪唑鎓三氟甲烷磺酸盐(CAS号:174899-66-2)的替代品?
在合成中,可以考虑使用1-正-丁基-3-甲基咪唑鎓溴酸盐或1-正-丁基-3-甲基咪唑鎓氯酸盐作为替代品。这些化合物在性能上与1-正-丁基-3-甲基咪唑鎓三氟甲烷...
2-methyl-5-thiophen-2-ylfuran-3-carboxylic acid(CAS号:651005-90-2)的市场或研究趋势如何?
目前,2-methyl-5-thiophen-2-ylfuran-3-carboxylic acid的研究主要集中在药物化学和新型材料领域。随着生物医药和有机合...
格列吡嗪杂质H(CAS号:13554-93-3)的主要用途是什么?
格列吡嗪杂质H主要作为药物中间体或副产物存在,并无特定的工业应用。在药物生产中,它可能需要被处理掉以保证最终药物的质量。
如何储存(9ci)-4-甲氧基-1H-苯并咪唑-2-乙腈(CAS号:317817-41-7)?
(9ci)-4-甲氧基-1H-苯并咪唑-2-乙腈应储存在阴凉、干燥、通风良好的地方,避免阳光直射。使用密封的玻璃或塑料容器储存,并确保容器的密封性良好,以防止挥...
4,5,9,10-四氢苯芘(CAS号:781-17-9)应用于哪些行业?
4,5,9,10-四氢苯芘在医药行业用于作为某些药物的中间体,在聚合物行业用作添加剂提升材料的热稳定性,在传感器领域作为传感器的敏感材料,在半导体行业中用作掺杂...
处理叶酸-D4(CAS号:171777-72-3)时应注意哪些实验室安全事项?
处理叶酸-D4时应佩戴个人防护装备(PPE),如手套和实验服。操作应在通风橱内进行,以避免吸入蒸汽或粉尘。如果不慎泄露,应立即用大量清水冲洗,并通知安全人员。参...
如何处理含有6-溴-2-(三氟乙酰基)-1,2,3,4-四氢异喹啉(CAS号:252331-63-8)的废料?
含有该化合物的废料应收集到专用的容器中,并进行密封以防止挥发和泄漏。在处理前,需进行危险性评估,以确定是否需要进行化学处理。最终处置需遵循当地的危险废物管理规定...
4,5-二氟-2-甲氧基苯甲醛(CAS号:145742-34-3)的主要用途是什么?
4,5-二氟-2-甲氧基苯甲醛主要用作有机合成中的中间体,特别是在制药和农药领域。它可以作为合成其他有机化合物的原料。
5-溴-6-三氟甲基吲哚(CAS号:1198475-24-9)安全吗?
5-溴-6-三氟甲基吲哚作为一种化学试剂,具有一定的毒性,需要在通风橱中操作,并采取适当的安全措施以避免吸入、皮肤接触和眼睛刺激。应避免与皮肤和眼睛直接接触,并...
来源期刊
Analyst

Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.











![Sodium 6-amino-3-[(E)-{4-[(E)-(4-aminophenyl)diazenyl]-2-methoxy-5-methylphenyl}diazenyl]-4-hydroxy-2-naphthalenesulfonate structure Sodium 6-amino-3-[(E)-{4-[(E)-(4-aminophenyl)diazenyl]-2-methoxy-5-methylphenyl}diazenyl]-4-hydroxy-2-naphthalenesulfonate structure](https://cnstatic.chemtradehub.com/structs/294/2945-96-2-092f.webp)


