The reaction between the methyl Criegee intermediate and hydrogen chloride: an FTMW spectroscopic study
文献信息
Carlos Cabezas, Yasuki Endo
Experiments using pulsed Fourier-transform microwave spectroscopy have been performed to probe the reaction between the methyl substituted Criegee intermediate, CH3CHOO, and hydrogen chloride. Two conformers of the product derived from the insertion of HCl within CH3CHOO, chloroethyl hydroperoxide, formed in the discharged plasma of a CH3CHI2/O2/HCl gas mixture, were identified through their experimentally determined rotational and quadrupole coupling constants. The relative abundance of the detected species indicates that the reaction of the anti-CH3CHOO conformer is faster than that of the syn-CH3CHOO conformer. The results presented in this work constitute the first experimental information about the reaction between CH3CHOO and HCl.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




