Metallocene influence on poly(cyclosilane) structure and properties
文献信息
Carlton P. Folster, Rebekka S. Klausen
Poly(cyclosilane)s, conjugated polymers inspired by crystalline silicon, are synthesized by group 4 metallocene-promoted dehydrocoupling polymerization. Changes in metallocene structure and reactivity are correlated with changes in poly(cyclosilane) chain length and optical properties. This work demonstrates the ability of target-directed synthesis to afford tunable, complex polymeric architectures.
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Polymer Chemistry

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