Micro-kinetic model of electrochemical carbon dioxide reduction over platinum in non-aqueous solvents
文献信息
Brian A. Rohr, Aayush R. Singh, Joseph A. Gauthier, Michael J. Statt, Jens K. Nørskov
The competition between the hydrogen evolution reaction and the electrochemical reduction of carbon dioxide to multi-carbon products is a well-known challenge. In this study, we present a simple micro-kinetic model of these competing reactions over a platinum catalyst under a strong reducing potential at varying proton concentrations in a non-aqueous solvent. The model provides some insight into the mechanism of reaction and suggests that low proton concentration and a high fraction of stepped sites is likely to improve selectivity to multi-carbon products.
期刊推荐

European Journal of Wood and Wood Products

Nature

Journal of Heterocyclic Chemistry

Journal of Medicinal Chemistry

Pharmacological Reviews

Fibre Chemistry

Helvetica Chimica Acta

Proceedings of the National Academy of Sciences of the United States of America

Journal of Catalysis

Organic Preparations and Procedures International
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来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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