Epoxidized 1,4-polymyrcene

文献信息

发布日期 2020-01-02

DOI 10.1039/C9PY01783F

影响因子 5.582

作者

Aleksandar Matic, Andreas Hess, Dirk Schanzenbach, Helmut Schlaad

查看原文

摘要

1,4-Polymyrcene was synthesized by anionic polymerization and epoxidized using meta-chloroperbenzoic acid. Samples with different degrees of epoxidation (25%, 49%, 74%, and 98%) were prepared and examined according to their chemical and thermal properties. Epoxidation was found to increase the glass transition temperature (Tg = 14 °C for the 98% epoxidized 1,4-polymyrcene) as well as the shelf live (>10 months). The trisubstituted epoxide groups were remarkably stable against nucleophiles under basic conditions but cross-linked or hydrolyzed in the presence of an acid. Also, highly epoxidized 1,4-polymyrcene readily cross-linked upon annealing at 260 °C to produce an epoxy resin.

期刊推荐

Tetrahedron Letters

Studies in Conservation

European Journal of Medicinal Chemistry

Progress in Materials Science

Applied Surface Science

Dyes and Pigments

Tetrahedron

Journal of Natural Products

Dental Materials

Applied Clay Science

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Epoxidized 1,4-polymyrcene

文献信息

期刊推荐

相关文献

Prediction of the electronic structure of single-walled black phosphorus nanotubes

High critical field NbC superconductor on carbon spheres

A molecular dynamics study of the ionic liquid, choline acetate

Molecular dynamics of anhydrous glycolipid self-assembly in lamellar and hexagonal phases

Inside front cover

Structural analysis of IPC zeolites and related materials using positron annihilation spectroscopy and high-resolution argon adsorption

Explanation of the size dependent in-plane optical resonance of triangular silver nanoprisms

Connectivity matters – ultrafast isomerization dynamics of bisazobenzene photoswitches

Analysis of the magnetically induced current density of molecules consisting of annelated aromatic and antiaromatic hydrocarbon rings

Pressure-induced structural and valence transition in AgO

您可能还喜欢

处理2-异丙基-5-羧基-1,3-二氧六环(CAS号：116193-72-7)时应注意哪些实验室安全事项？

2-Hydroxy-N,N-dimethyl-2-phenylacetamide(CAS号：2019-71-8)的市场或研究趋势如何？

4-(1H-吡唑-3-基)哌啶(CAS号：278798-08-6)应用于哪些行业？

什么是三氯噻嗪(CAS号：133-67-5)？

阿螺旋霉素(CAS号：467214-20-6)通常如何合成？

什么是2-(二甲基氨基)-5-硝基苯甲酸(CAS号：4405-28-1)？

1-苯基-1H-吡唑-4-甲酸甲酯(CAS号：7188-96-7)应用于哪些行业？

1-(三异丙基甲硅烷基氧基)环丙烷羧酸甲酯(CAS号：83010-83-7)应用于哪些行业？

(+)-蛇菰宁(CAS号：215319-47-4)安全吗？

如何处理含有对甲苯氧基乙酸肼(CAS号：36304-39-9)的废料？

来源期刊

Polymer Chemistry

推荐化合物

4,4''-Dichloro-1,1':2',1''-terphenyl

2-Methyl-2-propanyl 3-[2-(2-{[(4-methylphenyl)sulfonyl]oxy}ethoxy)ethoxy]propanoate

2,2,6-Trimethyl-1,4-cyclohexanedione

Dichloro(1,5-cyclooctadiene)palladium(II)

Anthracen-9-yl 2-methylprop-2-enoate

推荐供应商