Molecular structure and reactivity of a copper(I) tetramer

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DOI 10.1039/CC9960001081

影响因子 6.222

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摘要

A homoleptic copper(I) tetramer, [Cu(PhTt)]4 1, is synthesized using phenyltris[(methylthio)methyl)]borate, PhTt–; X-ray analysis shows the four copper ions are nearly coplanar and each resides in an approximately tetrahedral environment; although 1 is stable towards O2, H2O and CO, it reacts with PPh3, pyridine, or [NEt4]SPh to yield the corresponding monomer, [Cu(PhTt)L](L = PPh3 2, py 3, [NEt4]SPh 4).

期刊推荐

Journal of Physical Organic Chemistry

Journal of Computer-Aided Molecular Design

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Bio-Medical Materials and Engineering

来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Molecular structure and reactivity of a copper(I) tetramer

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