Oxygen tolerant, photoinduced controlled radical polymerization approach for the synthesis of giant amphiphiles

文献信息

发布日期 2021-03-18

DOI 10.1039/D0PY01608J

影响因子 5.582

作者

Alexis Theodorou, Petros Mandriotis, Athina Anastasaki, Kelly Velonia

查看原文

摘要

Amphiphilic protein–polymer conjugates form hybrid nanostructures with a broad range of potential applications. Herein, we expand the scope of amphiphilic protein–polymer bioconjugates via an oxygen tolerant, photoinduced RDRP method. A range of hydrophobic acrylic, methacrylic and acrylamide-based monomers are comprehensively screened to identify optimum reaction conditions that lead to quantitative biomacroinitiator consumption. By judiciously varying a number of components (e.g. monomer loading, catalyst concentration, pH, co-solvent, salt content), well-defined protein–polymer conjugates bearing different polymer moieties were obtained and their intrinsic properties were expressed through both their self-assembled architectures and esterase-like catalytic activity.

期刊推荐

Molecular Diversity

Angewandte Chemie International Edition

Coloration Technology

Journal of Enzyme inhibition and Medicinal Chemistry

Physical Chemistry Chemical Physics

Environmental Toxicology and Pharmacology

Advanced Engineering Materials

Photochemical & Photobiological Sciences

Journal of Medical Biochemistry

CrystEngComm

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Oxygen tolerant, photoinduced controlled radical polymerization approach for the synthesis of giant amphiphiles

文献信息

期刊推荐

相关文献

Solving the discrepancy between the direct and relative-rate determinations of unimolecular reaction kinetics of dimethyl-substituted Criegee intermediate (CH3)2COO using a new photolytic precursor

Effects of adatom species on the structure, stability, and work function of adatom-α-borophene nanocomposites

The radicals of quercetin-derived antioxidants in Triton X-100 micelles

Computational screening of functionalized MXenes to catalyze the solid and non-solid conversion reactions in cathodes of lithium–sulfur batteries

Cu2+-Induced self-assembly and amyloid formation of a cyclic d,l-α-peptide: structure and function

Ionic migration induced loss analysis of perovskite solar cells: a poling study

Polymer architecture dictates thermoreversible gelation in engineered emulsions stabilised with branched copolymer surfactants

Back cover

Multiple-cation wide-bandgap perovskite solar cells grown using cesium formate as the Cs precursor with high efficiency under sunlight and indoor illumination

Thermal tuning of terahertz metamaterial absorber properties based on VO2

您可能还喜欢

什么是2,6-二溴-4,8-双[(2-乙基己基)氧基]苯并[1,2-b:4,5-b']二噻吩(CAS号：1226782-13-3)？

木聚硫钠(CAS号：37319-17-8)的物理化学性质是什么？

2-甲氧基-4-(三氟甲基)苄溴, JRD(CAS号：886500-59-0)适用哪些法规指南？

1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulfinate(CAS号：119752-83-9)的主要用途是什么？

如何处理含有4-(Bromomethyl)-2-fluorobenzenesulphonamide(CAS号：1645275-47-3)的废料？

Loureiriol(CAS号：479195-44-3)的物理化学性质是什么？

在合成中是否有3-氨基苯甲酰苯胺(CAS号：14315-16-3)的替代品？

4-异氰酰苯基硼酸频哪醇酯(CAS号：380430-64-8)的市场或研究趋势如何？

如何储存3β-乙酰氧基-7,25-甘遂二烯-24(R)-醇(CAS号：1352001-09-2)？

如何储存4-氟-2-甲基-1H-吲哚(CAS号：1260383-51-4)？

来源期刊

Polymer Chemistry

推荐化合物

4-(Bromomethyl)-1-cyclohexyl-2-(trifluoromethyl)benzene

4-Methyl-2-oxo-2H-chromen-7-yl 2-acetamido-2-deoxy-3-O-(6-deoxy-alpha-L-galactopyranosyl)-beta-D-glucopyranoside

(1H-Pyrazol-4-yl)boronic acid hydrochloride

1-[4-(4-Methyl-1H-imidazol-1-yl)phenyl]ethanone

tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate

推荐供应商